ex1 Flashcards

1
Q

E2

A

ZAITSEV
HOFFMAN’S
ANTI-COPLANAR (180)

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2
Q

E1

A

ZAITSEV
REARRANGEMENTS

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3
Q

DEHYDRATION OF ALCOHOLS

A

(-HOH)

ZAITSEV
REARRANGEMENTS

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4
Q

ELECTROPHILIC ADDITION

A

(+ELE,NUC)

SYN-ADDITION

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5
Q

HYDROHALOGENATION

IONIZING

A

(+HX)

MARKOV
REARRANGEMENTS
SYN-ADDITION

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6
Q

HYDROHALOGENATION

FREE RADICAL ADDITION

A

(+HX)

ANTI-MARKOV
SYN-ADDITION

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7
Q

HYDRATION

ACID CATALYZED HYDRATION

A

(+HOH)

MARKOV
SYN-ADDITION
REARRANGEMENTS

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8
Q

HYDRATION

OXYMERCURATION-DEMERCURATION

A

(+HOH)

MARKOV
ANTI-ADDITION
MERCURIUM ION RING INTERMEDIATE

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9
Q

HYDRATION

HYDROBORATION

A

(+HOH)

ANTIMARKOV
SYN-ADDITION

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10
Q

ALKOXYMERCURATION DEMERCURATION

A

(+H,ETHER)
MARKOV
ANTI-ADDITION
MERCURIUM ION RING INTERMEDIATE

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11
Q

HALOGENATION

A

(+X2) +ENANTIOMER

ANTI-ADDITION
HALONIUM ION RING

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12
Q

HALOHYDRIDE FORMATION

A

(+XOH)

MARKOV
ANTI-ADDITION

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13
Q

CATALYTIC HYDROGENATION

A

(+H2)

SYN-ADDITION

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14
Q

ADDITION OF CARBENES

DIAZMETHANE

A

*CH2, TOXIC

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15
Q

ADDITION OF CARBENES

SIMMONS SMITH

A

*CH2, SAFER

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16
Q

ADDITION OF CARBENES

ALPHA-ELIMINATION OF HALOFORM

A

*CX2, RETAIN CIS/TRANS