Equlibrium Unit 3 Flashcards

1
Q

What is equilibrium?

A

When the rate of the forward reaction is equal to the rate of the reverse reaction

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2
Q

When is a reaction said to be in equilibrium

A

When the chemical reaction proceeds in both directions at the same time, and the amounts of reactants and products are staying constant

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3
Q

What are the determining factors of if a reaction is an equilibrium?

A

Constant colour
Constant temperature
Constant pressure
Constant concentration

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4
Q

What two equilibrium determining factors go together

A

Colour and concentration

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5
Q

Exothermic equation

A

A———> B+heat

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6
Q

Endothermic equation

A

A+heat———> B

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7
Q

Factors affecting equilibrium

A

Temperature
Concentration
Pressure

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8
Q

What does temperature do to equilibrium?

A

An increase in temperature causes the reaction to shift so an endothermic process is favoured.

It shifts to use up extra heat

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9
Q

What does concentration do to equilibrium?

A

An increase in concentration will cause the reaction to shift so the excess reactant or product is used up

Away from the side that the excess is on

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10
Q

What does pressure do to equilibrium?

A

An increase in pressure will cause a reaction to shift so the pressure is reduced

It will shift to the side that has the fewest moles of gas

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11
Q

What does a catalyst do to equilibrium?

A

It does not affect equilibrium

It causes equilibrium to be established sooner

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12
Q

What is LaChateliers principle

A

When a system is subjected to a stress, the system reacts to reduce the stress

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13
Q

Which way does the reaction shift if the temperature is increased?

A

Shifts left to reduce temperature

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14
Q

Which way does the reaction shift if the N2 is increased?

A

Shifts right to use up excess N2

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15
Q

What happens to the reaction when the pressure is reduced?

A

Shifts left to the side with more moles of gas

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16
Q

What does Keq mean

A

For in a reaction at a certain temperature, the ratio products to reactants is constant

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17
Q

Keq equation

A
18
Q

What is the keq value for this

A
19
Q

When are products favoured

A

If Keq is greater than 1

20
Q

When are reactants favoured

A

When Keq is less than 1

21
Q

What kind of compounds can be included in Keq

A

Only gas and aqueous

NO LIQUID OR SOLID

22
Q

What does ICE stand for

A

Initial
Change
Equilibrium

23
Q

Solve

A
24
Q

Find Keq

A
25
Q

What are the two factors that determine if a reaction reaches equilibrium, goes to completion, or does not react

A

Enthalpy
Entropy

26
Q

Enthalpy (letter)

A

Favours aside that the energy is on

H

27
Q

Entropy (letter)

A

Randomness- favours the side that is most random

S

28
Q

Randomness scale

A
29
Q

Entropy and Enthalpy for equilibrium

A
30
Q

Entropy and Enthalpy for completion

A
31
Q

Entropy and Enthalpy for no reaction

A
32
Q

Where does energy go if 📐H= -10Kj

A

On the right side

33
Q

Increase in temp

A
34
Q

Volume decreased

A
35
Q

N2 is removed

A
36
Q

Catalyst is added

A
37
Q

Draw the graph for an increase in temp

A
38
Q

Draw the graph for a decrease in volume

A
39
Q

Draw the graph for N2 being removed

A
40
Q

Draw the graph for a catalyst being added

A