Equlibrium Unit 3 Flashcards

1
Q

What is equilibrium?

A

When the rate of the forward reaction is equal to the rate of the reverse reaction

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

When is a reaction said to be in equilibrium

A

When the chemical reaction proceeds in both directions at the same time, and the amounts of reactants and products are staying constant

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

What are the determining factors of if a reaction is an equilibrium?

A

Constant colour
Constant temperature
Constant pressure
Constant concentration

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

What two equilibrium determining factors go together

A

Colour and concentration

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Exothermic equation

A

A———> B+heat

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Endothermic equation

A

A+heat———> B

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Factors affecting equilibrium

A

Temperature
Concentration
Pressure

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

What does temperature do to equilibrium?

A

An increase in temperature causes the reaction to shift so an endothermic process is favoured.

It shifts to use up extra heat

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

What does concentration do to equilibrium?

A

An increase in concentration will cause the reaction to shift so the excess reactant or product is used up

Away from the side that the excess is on

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

What does pressure do to equilibrium?

A

An increase in pressure will cause a reaction to shift so the pressure is reduced

It will shift to the side that has the fewest moles of gas

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

What does a catalyst do to equilibrium?

A

It does not affect equilibrium

It causes equilibrium to be established sooner

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

What is LaChateliers principle

A

When a system is subjected to a stress, the system reacts to reduce the stress

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Which way does the reaction shift if the temperature is increased?

A

Shifts left to reduce temperature

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Which way does the reaction shift if the N2 is increased?

A

Shifts right to use up excess N2

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

What happens to the reaction when the pressure is reduced?

A

Shifts left to the side with more moles of gas

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

What does Keq mean

A

For in a reaction at a certain temperature, the ratio products to reactants is constant

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

Keq equation

18
Q

What is the keq value for this

19
Q

When are products favoured

A

If Keq is greater than 1

20
Q

When are reactants favoured

A

When Keq is less than 1

21
Q

What kind of compounds can be included in Keq

A

Only gas and aqueous

NO LIQUID OR SOLID

22
Q

What does ICE stand for

A

Initial
Change
Equilibrium

23
Q

Solve

24
Q

Find Keq

25
What are the two factors that determine if a reaction reaches equilibrium, goes to completion, or does not react
Enthalpy Entropy
26
Enthalpy (letter)
Favours aside that the energy is on H
27
Entropy (letter)
Randomness- favours the side that is most random S
28
Randomness scale
29
Entropy and Enthalpy for equilibrium
30
Entropy and Enthalpy for completion
31
Entropy and Enthalpy for no reaction
32
Where does energy go if 📐H= -10Kj
On the right side
33
Increase in temp
34
Volume decreased
35
N2 is removed
36
Catalyst is added
37
Draw the graph for an increase in temp
38
Draw the graph for a decrease in volume
39
Draw the graph for N2 being removed
40
Draw the graph for a catalyst being added