Equlibria A Level Flashcards
Bronsted-lowry acid
proton donor
Bronsted-lowry base
proton acceptor
Monoprotic acid
donates 1 mole of protons per mole of acid
Diprotic acid
Donated 2 moles of proton per mole of acid
Degree of dissociation
fraction or percentage of molecules that dissociate into ions.
Kw
Kw=[H+] [OH-]
Ka
Ka= [H+][A-] / [HA]
pH of buffer solution
pH= pKa +log[salt]/[acid]
pH
pH=-log[H+]
pH of weak acids
pH=root(Ka × [HA])
What are Buffer solutions
Solutions that resist changes in pH when small amounts of acid or base is added
Why does Kw vary with temperature
- forward reaction of the dissociation of water is endothermic.
- increase in temperature favours the endothermic reaction.
- [H+] and [OH-] increase
- hence Kw increases
Neutral salt
strong acid + strong base
Acidic salt
strong acid + weak base
Basic salt
strong base + weak acid
Amphotheric / Neutral salts
weak acid + weak base
reaction quotient (Q)
determine if a precipitate will form with a given concentration of ions.
QKsp ~ precipitate will form
Kpc
Kpc= [X in organic] / [X in aqueous]
What is a buffer solution made of
weak acid with its conjugate base
weak base with conjugate acid
Buffer solution in blood
H2CO3 <=> HCO3- + H+
Other uses of buffer
baby lotion
shampoo
eyedrops