Equilibrium Flashcards

1
Q

what is equilibrium

A

Equilibrium can be defined as a state reached of a reversible reaction, in which the rate of the forward and backward reactions equal.

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2
Q

examples of equilibrium

A
  • water cycle

- closed water bottle

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3
Q

features of the equilibrium state

A
  • dynamic (ever changing, f and r reaction occurring at equal rate)
  • closed system (no change of matter with the surroundings)
  • concentration of products and reacts constant at equilibrium
  • no macroscopic change in properties (no visible change at blind eye)
  • can be reached from either direction
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4
Q

what is the equilibrium constant expression

A

Kc= [C]^c[D]^d/[A]^a[B]^b or

products/reactants

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5
Q

what does Kc indicate

A

the extent of the reaction under the conditions used

- it has no units

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6
Q

High Kc

A

a lot of products

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7
Q

low Kc

A

small amount of reactants converted to products

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8
Q

kc= 1

A

reaction at equilibrium

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9
Q

kc

A

reaction hardly goes

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10
Q

kc> 10^10

A

reaction complete

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11
Q

kc= 0.01

A

reactants predominate

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12
Q

kc= 100

A

products predominate

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13
Q

whats it the reaction quotients

A

Q= the Kc calculations when you don have concentration values/reaction isn’t at equilibrium

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14
Q

what is Le Chatelier principle

A
  • when a system at equilibrium is disturbed, the equilibrium position will shift in the direction which tends to minimize, or counteract, the effect of the disturbance
    LIKE DIFFUSION
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15
Q

how do catalysts affect equilibrium position

A
  • they don’t. But it does affect the speed at which the reaction reaches equillibiurm
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