equilibrium 2 p1 Flashcards
partial pressure
each gas’s contribution to the total pressure
partial pressure p = mole fraction x total pressure
mole fraction
moles of gas / total number of moles of gas in the mixture
what does a Kp equation look like?
pCc x pDd/pAa x pBb
pA = partial pressure of A and a = number of moles of A
units - work out for each reaction using the units given e.g. Pa, atm, etc
how does increased temperature of an endothermic reaction effect Kp?
equilibrium shifts to the right, so partial pressure of products increase, so Kp increases
how does decreased temp of an endothermic reaction effect Kp?
equilibrium shifts to the left, so partial pressure of reactants increase, so Kp decreases
how does pressure affect the value of Kp?
it doesn’t
how does increased temp or pressure affect any reaction?
temp - more particles have energy greater than or equal to the activation energy –> more successful collisions per second
pressure - more particles in the same volume –> more successful collisions per second