equilibrium Flashcards

1
Q

dynamic

A

constant, active movement

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2
Q

static

A

without motion, fixed

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3
Q

constant

A

ultimately not changing visually

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4
Q

rate

A

typically a ratio in referrence to time

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5
Q

example of rate

A

speed- distance over time

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6
Q

properties of a system in chemical equilibrium

A
  1. closed system
  2. macroscope properties are constant
  3. equal rate of forward and reverse
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7
Q

dynamic equilibrium

A

dynamic- reactions still happening
equilibrium- rate of forward reaction is equal to rate of the reverse reaction

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8
Q

macroscopic properties

A

color
pressure
concentration

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9
Q

is dynamic equilibrium 50/50

A

not neccesarily

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10
Q

strong acid willing to give up

A

hydrogen

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11
Q

quantitative reactions

A

start out as reactants, go till completion, end up as products
-doesnt apply to all reactions

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12
Q

equilibrium constants

A

must consider reaction and product concentrations at the time equilibrium is reached
-experimental

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13
Q

Keq or Kc

A

product of molar concentrations of the product for the chemical reaction

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14
Q

rules of Kc

A

-concentrations always mol/L
-product concentrations are numerator
-reactant concentrations are placed in the denominator
-powers determinded by balanced equation

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15
Q

what types of states concentrations are included in Kc equations

A

-only gases and substances in solutions

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16
Q

Kc > 1

A

more inclined to create product

17
Q

Kc < 1

A

reactant favoured

18
Q

factors that affect equilibrium

A
  1. diff chemical reactions of different Kc
  2. temperature
19
Q

Kc is ____ specific

A

temperature

20
Q

factors that DO NOT affect equilibrium

A
  1. adding/removing the reactant or product (just reestablishes equilibrium)
  2. catalysts (reaches equilibrium faster)
  3. change in pressure (reestablishes)
21
Q

using a graph to determine Kc what value do we use

A

equilibrium concentrations

22
Q

la chateliers principal

A

if a stress is applied to a system at equilibrium then the system will chabnge to relieve that stress

23
Q

energy (la chateliers principal)

A

energy is same as adding or removing chemical

24
Q

endothermic energy addition

A

energy is a reactant
-adding energy pushes the reaction to product/right

25
Q

exothermic energy addition

A

energy is a product
-adding energy, reaction shifts left (reactants)

26
Q

pressure in la chateliers principal

A

in an equilibrium system involving gases
-relieve system by making fewer molecules if inc of pressure

27
Q

temperature changes in graph

A

each identity will change, reactants the same, products the same

28
Q

pressure changes in graph

A

spike up of concentration due to smaller volume (pressure inc)
-system tries to relieve inc of pressure by making fewer molecules

29
Q

concentration changes in graph

A

-only one spike, everything else adjusts slowly
“use up the extra”

30
Q

graph if everything spikes

A

-pressure

31
Q

graph if one thing spikes

A

-concentration

32
Q

graph if there is change across all

A

-energy