Equilibrium Flashcards

1
Q

What is meant by dynamic equilibrium?

A

when concentration of reactants keep decreasing and the concentration of products keep increasing; the state where both concentrations are equal is called dynamic equilibrium.

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2
Q

What is meant by ionic equilibrium?

A

The equilibrium that deals with ions in aqueous medium is called ionic equilibrium.

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3
Q

What is Henry’s Law?

A

the mass of gas dissolved in a given mass of a solvent at any temperature is proportional to the pressure of the gas above the solvent.

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4
Q

What is equilibrium mixture?

A

A mixture of product and reactant in equilibrium

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5
Q

What is active mass?

A

It is the simple ratio of many things:
n/v
it was known as an alias for concentration in the olden days

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6
Q

What is law of mass action?

A
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7
Q

What is the relation between Kf and Kb

A

Kf=1/Kb

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8
Q

What is homogeneous equilibria?

A

The reactants and products in equilibria are in the same phase.

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9
Q

What is the equilibrium constant in gaseous systems?

A

Kp=Kc RT^delta ng

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10
Q

State Le Chatelier’s Principle

A

a change in any factors that determine the equilibrium of a system will cause the system to shift its equilibrium as a counteract to the change.

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11
Q

Whats the difference between strong and weak electrolyte?

A

Strong electrolytes dissociate completely while weak electrolytes dissociate partially

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12
Q

What is the difference between dissociation and ionisation constant?

A

Diss- the separation of ions in water already existing as such in solid form- eg.sodium chloride
ions-the separation of a neutral molecule into charged ions in solution

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13
Q

State Arrhenius theory

A

Arrhenius acid: dissociate to give H+
Arrhenius base: dissociate to give OH-

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14
Q

What is the Bronsted-Lowry theory?

A

Acid- donates H+
Base- accepts OH-

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15
Q

Relationship between Kp and Kc

A

Kp=Kc(RT)delta ng

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16
Q

As volume decreases what happens to pressure and no of moles

A

V increases P increases n of pdt decreases

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17
Q

How does temperature affect equilibrium

A

Log K2/K1=delta H/2.303 R (1/T1+ 1/T2)

Kf= A^Ef /RT

18
Q

What is reaction quotient

A

The ratio of concentration during anytime of the reaction which helps predict the direction of reaction

If Q>K reverse
If Q<K forward
If Q=K equilibrium

19
Q

What is degree of dissociation

A

Alpha is the fraction of one mole dissociated into the products

=D-d/(n-1)d
D=vp without dissociation
d=vp of mixture

20
Q

Delta H for endothermic and exothermic

A

Exo-
Endo +

21
Q

Condition for spontaneity

A

Delta G < 0

22
Q

What is Arrhenius acid

A

Donated H+

23
Q

What is Arrhenius base

A

Donates OH-

24
Q

What is Bronsted acid

A

Donates H+

25
Q

What is Bronsted base

A

Accepts H+

26
Q

What is Lewis acid

A

Accepts lp

27
Q

What is Lewis base

A

Donates lp

28
Q

H3BO3 is a _______ acid

A

Arrhenius

29
Q

How do you arrive with conjugate acid

A

Base + H+ -> Conjugate acid

30
Q

What is conjugate base

A

Acid -> Conjugate base + H+

31
Q

Hiw are ph and poh connected?

A

Ph = -log[H+]
Poh=-log[OH-]

Ph + Poh = 14 for 25 degrees Celsius
Ph + Poh = 12 for 90 degrees Celsius

32
Q

For [H+] < 10^-6

A

Add conc of water 10^-7
Usually get answer 6.9

33
Q

pH of 2SA or 2SB

A

M1v1nf1+M2v2nf2/v1+v2

34
Q

pH of 1SA 1SB

A

Im1v1nf1-m2v2nf2l/v1+v2

35
Q

pH of weak mono acidic or basic

A

Alpha = root Kh/C

36
Q

pH of weak poly acidic or basic

A

1/2(pKa-logC)

37
Q

pH of amphiprotic

A

Pka1 + Pka2/2

38
Q

What is Kw

A

[H+][OH-]

39
Q

What is pKw

A

pH + pOH = pKw = 14

40
Q

What is Kw

A

Ionic product of water