Equilibria Flashcards

1
Q

rate of reaction

A

the amount of product that is made in a reaction in a specified time period

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2
Q

what is dynamic equilibrium

A

when rate of forward reaction same as backward reaction

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3
Q

features of dynamic equilibrium

A

-concentrations of reactants and products dont change
-in closed system

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3
Q

features of reaction at equilibrium

A

rates of forward and backward reactions are equal
-reactant and product concentrations are constant
-rates of forward and backward reactions are constant

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4
Q

effect on equilibrium when temp increases

A

moves in direction of the endothermic reaction

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5
Q

effect of equilibrium when temp decreases

A

-moves in the direction of the exothermic reaction

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6
Q

what does lachateliers principle state

A

if any factor that affects the equilibrium changes, then the equilibrium position will move to counteract the change

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7
Q

exam question how yield of product would change if factor effecting equilibrium changes

A

1-is pressure change which side has more molecules, if temp forward or backward exothermic
2-is position changes to left or right
3-why position changes- to counteract change
4-how change effects yield

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8
Q

why dont catalysts effect equilibrium position

A

because increases rate of forward and backward reaction equally

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9
Q

compromise conditions

A

temp not to high as could decrease yield of ammonia but not to low to decrease rate of reaction

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10
Q

conditions used for increasing yield of ammonia

A

liquidify ammonia to reduce gaseous ammonia
-use iron catalyst

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11
Q

how to compare concentrations at equilibrium

A

divide conc of products by reactants

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12
Q

what happens as value Kc increases

A

reactant to product equilibrium increases

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13
Q

equilibrium constant of concentration
-Kc

A

8.3 times 10 to the 4

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14
Q

equation for Kc

A

conc of products/ conc of reactants

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15
Q

how to calculate Kc value

A

substitute values into expression for Kc
-evaluate
-determine whether constant has units

16
Q
A