EPR and X-ray crystallography Flashcards

1
Q

EPR

A

microwave energy absorbed by paramagnetic species (contains unpaired electrons)

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2
Q

Hyperfine splitting

A

2nI+1

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3
Q

X-ray Crystallography

A

regular 3D array of atoms form planes.

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4
Q

Bragg’s Law

A

n(wavelength) = 2dsin(theta). In order for constructive interference to occur and a reflection to be observed, must be satisfied.

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5
Q

Intensity of reflections determined by

A

position of atoms in the lattice. Type of atom.

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6
Q

Space group

A

group of symmetry operations that describe how molecules are arranged in the unit cell

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7
Q

Asymmetric units

A

related by symmetry, substructures within the unit cell

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