Enthalpy Definitions (Chemistry) Flashcards

1
Q

Define: Enthalpy of Formation

A

Enthalpy change when 1 mole of substance is formed from its constituent elements with all substances in their standard states:

2Na(s) + 1/2 O2(g) –> Na2O(s)

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2
Q

Define: Enthalpy of Combustion

A

Enthalpy change when 1 mole of substance undergoes complete combustion in oxygen with all substances in standard states

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3
Q

Define: Enthalpy of neutralisation

A

Enthalpy change when 1 mole of water is formed in a reaction between an acid and alkali under standard conditions

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4
Q

Define: First Ionisation Enthalpy

A

enthalpy change when each atom in one mole of gaseous atoms loses one electron to form one mole of gaseous 1+ ions

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5
Q

Define: Second ionisation energy

A

enthalpy change when each ion in one mole of gaseous 1+ ions loses one electron to form one mole of gaseous 2+ ions

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6
Q

Define: First Electron Affinity

A

enthalpy change when each atom in one mole of gaseous atoms gains one electron to form one mole of gaseous 1- ions

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7
Q

Define Second Electron Affinity

A

enthalpy change when each atom in one mole of gaseous 1- ions gains one electron to form one mole of gaseous 2- ions

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8
Q

Define: Enthalpy of atomisation

A

enthalpy change when one mole of gaseous atoms is produced from an element in its standard state

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9
Q

Define: Hydration Enthalpy

A

Enthalpy change when one mole of gaseous ions becomes hydrated

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10
Q

Define: Enthalpy of Solutions

A

Enthalpy change when one mole of solute is dissolved in a solvent

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11
Q

Define: Bond Dissociation of Formation

A

Enthalpy change when one mole of covalent bonds is broken in the gaseous state

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12
Q

Define: Lattice Enthalpy of Formation

A

enthalpy change of when one mole of a solid ionic compound is formed from its constituent ions in the gas phase

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13
Q

Define: Lattice Enthalpy of Disassociation

A

enthalpy change of when one mole of a solid ionic compound is broken up into its constituent ions in the gas phase

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14
Q

Define: Enthalpy of vaporisation

A

Enthalpy change when one mole of a liquid is turned into gas

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15
Q

Define: Enthalpy of Fusion

A

Enthalpy change when one mole of a solid is turned into liquid

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16
Q

Which enthalpy change has the symbol: f

A

formation

17
Q

Which enthalpy change has the symbol: c

A

combustion

18
Q

Which enthalpy change has the symbol: neut

A

neutralisation

19
Q

Which enthalpy change has the symbol: ie

A

Ionisation

20
Q

Which enthalpy change has the symbol: ea

A

electron affinity

21
Q

Which enthalpy change has the symbol: at

A

atomisation

22
Q

Which enthalpy change has the symbol: hyd

A

hydration

23
Q

Which enthalpy change has the symbol: sol

A

solution

24
Q

Which enthalpy change has the symbol: dis

A

bond dissociation

25
Q

Which enthalpy change has the symbol: LEF

A

lattice formation

26
Q

Which enthalpy change has the symbol: LED

A

lattice dissociation

27
Q

Which enthalpy change has the symbol: vap

A

vaporisation

28
Q

Which enthalpy change has the symbol: fus

A

fusion

29
Q

Define: Average Bond Enthalpy

A

the energy needed to break one mole of a given bond in a gaseous molecule

30
Q

Define: first ionisation energy

A

the energy required for the removal of 1 mol of electrons from 1 mol of gaseous atoms

31
Q

Define: Activation energy

A

the energy required to break bonds that act as a barrier to a reaction

32
Q

Define: Enthalpy of Reaction

A

the enthalpy change that accompanies a reaction in the molar quantities as shown in a chemical equation at STC and STS

33
Q

Which enthalpy change has the symbol: r

A

reaction