Enthalpy Definitions (Chemistry) Flashcards
Define: Enthalpy of Formation
Enthalpy change when 1 mole of substance is formed from its constituent elements with all substances in their standard states:
2Na(s) + 1/2 O2(g) –> Na2O(s)
Define: Enthalpy of Combustion
Enthalpy change when 1 mole of substance undergoes complete combustion in oxygen with all substances in standard states
Define: Enthalpy of neutralisation
Enthalpy change when 1 mole of water is formed in a reaction between an acid and alkali under standard conditions
Define: First Ionisation Enthalpy
enthalpy change when each atom in one mole of gaseous atoms loses one electron to form one mole of gaseous 1+ ions
Define: Second ionisation energy
enthalpy change when each ion in one mole of gaseous 1+ ions loses one electron to form one mole of gaseous 2+ ions
Define: First Electron Affinity
enthalpy change when each atom in one mole of gaseous atoms gains one electron to form one mole of gaseous 1- ions
Define Second Electron Affinity
enthalpy change when each atom in one mole of gaseous 1- ions gains one electron to form one mole of gaseous 2- ions
Define: Enthalpy of atomisation
enthalpy change when one mole of gaseous atoms is produced from an element in its standard state
Define: Hydration Enthalpy
Enthalpy change when one mole of gaseous ions becomes hydrated
Define: Enthalpy of Solutions
Enthalpy change when one mole of solute is dissolved in a solvent
Define: Bond Dissociation of Formation
Enthalpy change when one mole of covalent bonds is broken in the gaseous state
Define: Lattice Enthalpy of Formation
enthalpy change of when one mole of a solid ionic compound is formed from its constituent ions in the gas phase
Define: Lattice Enthalpy of Disassociation
enthalpy change of when one mole of a solid ionic compound is broken up into its constituent ions in the gas phase
Define: Enthalpy of vaporisation
Enthalpy change when one mole of a liquid is turned into gas
Define: Enthalpy of Fusion
Enthalpy change when one mole of a solid is turned into liquid
Which enthalpy change has the symbol: f
formation
Which enthalpy change has the symbol: c
combustion
Which enthalpy change has the symbol: neut
neutralisation
Which enthalpy change has the symbol: ie
Ionisation
Which enthalpy change has the symbol: ea
electron affinity
Which enthalpy change has the symbol: at
atomisation
Which enthalpy change has the symbol: hyd
hydration
Which enthalpy change has the symbol: sol
solution
Which enthalpy change has the symbol: dis
bond dissociation
Which enthalpy change has the symbol: LEF
lattice formation
Which enthalpy change has the symbol: LED
lattice dissociation
Which enthalpy change has the symbol: vap
vaporisation
Which enthalpy change has the symbol: fus
fusion
Define: Average Bond Enthalpy
the energy needed to break one mole of a given bond in a gaseous molecule
Define: first ionisation energy
the energy required for the removal of 1 mol of electrons from 1 mol of gaseous atoms
Define: Activation energy
the energy required to break bonds that act as a barrier to a reaction
Define: Enthalpy of Reaction
the enthalpy change that accompanies a reaction in the molar quantities as shown in a chemical equation at STC and STS
Which enthalpy change has the symbol: r
reaction