Enthalpy definitions Flashcards
standard enthalpy change of reaction
the enthalpy change that accompanies a reaction in the molar quantities shown in a chemical equation under standard conditions and standard states
standard enthalpy change of formation
the enthalpy change that accompanies the formation of one mole of a compound from its elements under standard conditions and standard states
standard enthalpy change of combustion
the enthalpy change that occurs when one mole of a substance reacts completely with oxygen under standard conditions in standard states
enthalpy change of neutralisation
the enthalpy change that accompanies the reaction of an acid and a base to form one mole of water under standard conditions in standard states.
average bond enthalpy
the energy required to break 1 mole of bonds in gaseous molecules
activation energy
the minimum energy required for a reaction to take place. the energy input required to break bonds
the role of a catalyst
Increase rate of reaction without being used up. To provide an alternate reaction route with lower activation energy
homogenous catalyst
same state as reactants
eg. ozone depletion/ esterification
heterogenous catalyst
different state to reactants
eg. alkene hydrogenation
dynamic equilibrium
rate of forward reaction is equal to the rate of the backwards reaction, concentrations of products and reactants remain constant
must be in a closed system