Enthalpy changes for solid + solution Flashcards
what is hess’s law
the energy change of any reaction is the same, regardless of route taken
where is more chemical energy present in an exothermic reaction
reactants > products
where is more chemical energy present in an endothermic reaction
reactants < products
which ways do the arrows point in enthalpy of formation
up
which ways do the arrows point in enthalpy of combustion
down
what are the standard conditions
- 298K
- 1mol/dm³ conc
- 1atm
what is enthalpy of solution used for
indicates if a substance should dissolve
how to calculate enthalpy of solution
= lattice - hydration
what does a negative enthalpy of solution mean
it should be spontaneously soluble at that temperature
stable
what does a small positive enthalpy of solution mean
will dissolve as energy is used from solution
unstable
what does a large positive enthalpy of solution mean
unlikely to dissolve at that temperature
unstable
increased temperature =
increased solubility
what are the 5 steps of Born Haber Cycles
….enthalpy of formation
(ionic solid)
1. atomisation
2. Ionisation
3. Atomisation
- Electron affinity
- Lattice formation