Enthalpy Changes Flashcards
What is an exothermic reaction?
One where the products have less enthalpy than the reactants, so excess energy is released as heat
Eg oxidation of fuels by combustion
Endothermic processes require…
Why do they require this?
Give one example of an endothermic reaction
An input of energy
The products have more energy than the reactants, so energy must be absorbed from the surroundings
Eg the thermal decomposition of calcium carbonate
Give one natural process that is exothermic
Respiration
Give one natural process that is endothermic
Photosynthesis
Standard conditions definition
1atm, 25*C, 1.0 moldm^-3
Enthalpy change of reaction definition
The enthalpy change that accompanies a reaction in the molar quantities expressed in a chemical equation under standard conditions, all reactants and products being in their standard states
Standard enthalpy change of combustion definition
The enthalpy change that takes place when one mole of a substance reacts completely with oxygen under standard conditions, all reactants and products being in their standard states
Standard enthalpy change of formation definition
The enthalpy change that takes place when one mole of a compound is formed from it’s constituent elements in their standard states under standard conditions
Bond breaking is…
Endothermic
Bond making is…
Exothermic
Average bond enthalpy definition
The average enthalpy change that takes place when breaking by homolytic fission 1 mol of a given type of bond in the molecules of a gaseous species