Basic Concepts Flashcards

0
Q

Functional group definition

A

A group of atoms responsible for the characteristic reactions of a compound

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
1
Q

Homologous series definition

A

A series of organic compounds having the same functional group but with each successive member differing by CH2

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

What are the names of the first 10 members of the alkanes homologous series?

A
Methane
Ethane
Propane
Butane
Pentane
Hexane
Heptane
Octane
Nonane
Decane
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Formula, prefix and suffix of an alcohol

A

-OH
Hydroxy-
-ol

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Formula and suffix of an aldehyde

A
  • CHO

- al

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Formula and suffix of a ketone

A

C-CO-C

-one

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Formula and suffix of a carboxylic acid

A
  • COOH

- oic acid

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

When naming compounds, an aldehyde is always on…

A

Carbon-1

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

When naming a compound with more than one group attached to it, the groups are listed…

A

Alphabetically

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Structural isomers definition

A

Compounds with the same molecular formula but different structural formulas

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Stereoisomers definition

A

Compounds with the same structural formula but a different arrangement of atoms in space

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

E/Z isomerism is…

A

An example of stereoisomerism. It occurs because of restricted rotation around a C=C bond and when 2 different groups of atoms are attached to each carbon of the C=C bond

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

What is Cis-trans isomerism

A

A special case of E/Z isomerism in which 2 of the substituent groups are the same

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

The E isomer looks like…

A

Z

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

The Z isomer looks like…

A

E

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

The cis isomer looks like…

A

C

16
Q

The trans isomer looks like…

A

Z

17
Q

What is homolytic fission?

A

A type of bond breaking where each atom in the covalent bond receives an electron from the bond, forming 2 radicals

18
Q

What is heterolytic fission?

A

A type of bond breaking in which one atom in the covalent bond receives both of the electrons from the bond, forming a cation and an anion

19
Q

What is a curly arrow?

A

An arrow that represents the movement of an electron pair, showing either breaking or formation of a covalent bond

20
Q

Percentage yield =

A

Actual yield / theoretical yield x 100%

21
Q

Atom economy =

A

Molecular mass of desired products / sum of molecular masses of all products x 100%

22
Q

Which reactions are more efficient, addition reactions or substitution reactions, and why?

A

Addition reactions are more efficient because they have 100% atom economy whereas substitution reactions produce some by-products and are less efficient. These by-products have to be disposed of, which is expensive, and landfill space is running out.

23
Q

What are the benefits of developing chemical processes with a high atom economy?

A

There are fewer waste materials