Enthalpy Change Definitions Flashcards
Enthalpy change of formation
1 mole of a compound is formed from its elements
Enthalpy change of atomisation
ONE mole of GASEOUS atoms is formed from the element
s -> g
First ionisation energy
Enthalpy change required to remove ONE electron from EACH atom in ONE mole of gaseous atoms to form ONE mole of gaseous 1+ ions
Electron affinity
Enthalpy change that takes place when ONE electron is added to EACH atom in ONE mole of gaseous atoms to form ONE mole of gaseous 1- ions
(Opposite of First ionisation energy)
Lattice enthalpy
ONE mole of a SOLID ionic compound is formed from its GASEOUS ions
Standard enthalpy change of reaction
Yes
Standard enthalpy change of combustion
ONE mole of a compound completely reacts with oxygen
Standard enthalpy change of neutralisation
An acid and base react to form ONE mole of water
Standard enthalpy change of solution
ONE mole of a solute DISSOLVES in a solvent, hence solution
s + aq -> +aq + -aq
Enthalpy change of hydration
Dissolving of GASEOUS ions to form ONE mole of AQUEOUS ions
g + aq -> aq
What is entropy?
The dispersal of energy within the chemicals making up the chemical system.
What is standard entropy?
The entropy of one mole of a substance under standard conditions.
JK-1mol-1
Always POSITIVE
What is the Gibbs equation?
G = #H - T#S
#G = Free energy change “Overall change in energy during a chemical reaction.”
= the triangle
What is feasibility?
Whether a reaction is able to happen and is energetically feasible.