Enthalpy Change Flashcards
What can cause enthalpy change to vary?
Conditions used
Enthalpy change can vary slightly depending on the conditions under which measurements are made.
What is the standard condition used for?
Physical measurements such as enthalpy change
Standard condition is important for consistency in measurements.
How is a standard physical value indicated in data tables?
Using a special standard sign ‘⦵’
This sign denotes values measured under standard conditions.
What does a standard enthalpy change ΔH° refer to?
An enthalpy H change Δ under standard conditions ⦵
Units are usually KJ mol-1.
What is the standard pressure in kPa?
100 KPa
This is close to one atmosphere, which is 101 KPa.
What is the standard temperature usually stated in Kelvin?
298 K
This is equivalent to 25℃.
What is the standard concentration for solutions?
1 mol dm-³
This applies specifically for solutions.
What defines the standard state of a substance?
The physical state under standard conditions
Most data tables show standard state at 100 kPa and 298 K.
What is the standard enthalpy change of a reaction ΔRH°?
Enthalpy change accompanying a reaction in molar quantities shown under standard conditions
This refers to the specific amounts in the balanced equation.
What does the standard enthalpy change of formation ΔFH⦵ represent?
Enthalpy change when one mole of a compound is formed from its elements under standard conditions
This is a key concept in thermodynamics.
For an element, what does ΔFH° refer to?
Formation of one mole of an element from its element
This reflects a unique case for elemental substances.
What is the standard enthalpy change of combustion ΔCH°?
Enthalpy change when one mole of a substance reacts completely with oxygen under standard conditions
This is crucial for understanding energy release in reactions.
What does the standard enthalpy change of neutralisation ΔneutH°?
Energy change during a neutralisation reaction where 1 mole of H₂O is formed under standard conditions
This highlights the energy dynamics in acid-base reactions.