Covalent Bonding Flashcards
Covalent bond
Electrostatic force of attraction between a shared pair of electrons and the nuclei of the bonded atoms.
covalent bond occurs between
Atmos in:
* Non-metallic elements, for example, H2 and O2
* Compounds of non-metallic elements, for example, H2O and CO2
* Polyatomic ions, for example, NH4+
How a covalent bond forms
- overlap of atomic orbitals, each containing one electron, to give a shared pair of electrons.
- atoms are held together by the attraction of the positive nuclei to the pair of negative electrons in the bonding orbitals. This attraction is the covalent bond.
Single covalent bonding
The electrostatic force of attraction between ONE shared pair of electrons and the nuclei of two bonded atoms
Multiple Covalent bonding
electrostatic force of attraction between more than one shared pair of electrons and the nuclei of two bonded atoms
Octet Rule
Electrons are shared so that atoms achieve a stable structure of 8 electrons in the outer shell similar to the noble gases
Exceptions to the Octet Rule
- Sulphur, phosphorus and chlorine
- Their outer shell electrons are in the n=3 shell. The n = 3 shell can occupy 18 electrons in total.
- Therefore it’s possible to have more than 8 electrons
Dative Covalent bond
type of covalent bond where one atom supplies both the shared pair of electrons to the covalent bond.
How to Determine covalent bond strength
- To determine the bond strength of a particular bond, an average of the energy required to break the bond in different structures containing that bond is taken.
- The larger the value of the average bond enthalpy, the stronger the covalent bond.