Covalent Bonding Flashcards

1
Q

Covalent bond

A

Electrostatic force of attraction between a shared pair of electrons and the nuclei of the bonded atoms.

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2
Q

covalent bond occurs between

A

Atmos in:
* Non-metallic elements, for example, H2 and O2
* Compounds of non-metallic elements, for example, H2O and CO2
* Polyatomic ions, for example, NH4+

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3
Q

How a covalent bond forms

A
  • overlap of atomic orbitals, each containing one electron, to give a shared pair of electrons.
  • atoms are held together by the attraction of the positive nuclei to the pair of negative electrons in the bonding orbitals. This attraction is the covalent bond.
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4
Q

Single covalent bonding

A

The electrostatic force of attraction between ONE shared pair of electrons and the nuclei of two bonded atoms

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5
Q

Multiple Covalent bonding

A

electrostatic force of attraction between more than one shared pair of electrons and the nuclei of two bonded atoms

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6
Q

Octet Rule

A

Electrons are shared so that atoms achieve a stable structure of 8 electrons in the outer shell similar to the noble gases

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7
Q

Exceptions to the Octet Rule

A
  • Sulphur, phosphorus and chlorine
  • Their outer shell electrons are in the n=3 shell. The n = 3 shell can occupy 18 electrons in total.
  • Therefore it’s possible to have more than 8 electrons
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8
Q

Dative Covalent bond

A

type of covalent bond where one atom supplies both the shared pair of electrons to the covalent bond.

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9
Q

How to Determine covalent bond strength

A
  • To determine the bond strength of a particular bond, an average of the energy required to break the bond in different structures containing that bond is taken.
  • The larger the value of the average bond enthalpy, the stronger the covalent bond.
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