Enthalpy and Hess' cycle Flashcards
enthalpy(H)
all the heat energy that is stored in a chemical system
enthalpy change (ΔH)
products - reactants
enthalpy profile
y = enthalpy
x = progress of reaction
Ea = reactants to peak
ΔH = reactants to products
standard enthalpy change (ΔH°)
.298 K
.100 kPa
.1 mol
.all chemicals in their standard states
standard enthalpy change of combustion (ΔcH°)
when one mole of a substance reacts completely with oxygen under standard conditions
standard enthalpy change of neutralisation (ΔnH°)
.one mole of water is formed in a neu reaction under standard conditions
standard enthalpy change of formation (ΔfH°)
when one mole of a compound is formed from its elements under standard conditions
standard enthalpy change of reaction (ΔrH°)
when a reaction takes place in the molar quantities shown by the balanced chemical equation under standard conditions
thermal energy
q = mcΔT
q = energy change in J
m = mass of water in g
T = temp change of water
calculating ΔcH° and ΔrH°
thermal energy(KJ)/num of moles
.always negative