Enthalpy Flashcards
Lattice Enthalpy ∆HLE
The enthalpy change that occurs when one mole of an ionic lattice is formed from its isolated gaseous ions
Entalpy Of Formation ∆Hf
The enthalpy change that occurs when one mole of a compound is formed from its elements in their standard states
Enthalpy Change Of Atomisation ∆HAT
The Enthalpy Change that occurs when one mole of gaseous atoms are formed from an element
First Ionisation Energy
The Energy required to remove one mole of electrons from one mole og gaseous atoms to form one mole of gaseous 1+ ions
Electron Affinity
Enthalpy change when one mole of gaseous atoms acquires one mole of electrons to form one mole of 1- ions.
Enthalpy Change of Hydration ∆Hhyd
enthalpy change that occurs when one mole of gaseous ions dissolves in (an excess of) water (to give an infinitely dilute solution)
Enthalpy Change of Solution ∆Hsol
The enthalpy change that occurs when one mole of a solute dissolves (in an excess of) solvent (to give an infinitely dilute solution)
Born Haber Cycle…
with MgCl2
1) enthalpy of formation of MgCl2
2) enthalpy of atomisation of Mg
3) enthalpy of atomisation of Cl x2
4) 1st ionisation energy of Mg
5) 2nd ionisation energy of Mg
6) Electron affinity of Cl x2
7) Lattice enthalpy of MgCl2
1,-2,-3,-4,-5=6+7
Born Haber With Enthalpy of Sol
Hydration Enthalpy = Lattice ethalpy + Enthalpy of Solution