Engineering - Thermodynamics Flashcards
In the equation ΔQ = Δu + ΔW
What does each stand for?
ΔQ: heat transfer to gas
Δu: increase in internal energy
ΔW: work done by gas
In the equation ΔQ = Δu + ΔW
What does it mean if Q is negative?
Energy transfers out of the system
In the equation ΔQ = Δu + ΔW
What does it mean if u is negative?
Internal energy has decreased
In the equation ΔQ = Δu + ΔW
What does it mean if w is negative?
Work is done on the system by external action
Energy transfers into the system
State the first law of thermodynamics
The change in internal energy of a system (Δu) is equal to the sum of the energy entering the system by heating (ΔQ) and the energy entering the system through work being done on it (ΔW)
Define adiabatic
No heat energy is transferred
What are the requirements for an adiabatic change?
Action is quick
Negligible transfer to surroundings
ΔQ=0
Outline an adiabatic compression by a piston on a gas
Perfect insulator between gas and surroundings
When piston pushed down, gas is compressed and work is done on the gas
Δu = ΔW
Temperature increases as u increases
Why does temperature of a gas fall when it expands adiabatically?
Work is done at the expense of internal energy
Outline an isothermal compression by a piston on a gas
Work is done on the gas as the piston moves down
Perfect conductor between gas and surroundings which allows free flow of heat
As gas is compressed, heat escapes so there is no change in temperature (Δu=0)
-ΔQ=ΔW
In an ideal gas, what is u?
The Ek of its molecules
Where does pressure in a piston come from?
Gas molecules colliding with external walls
Prove that W=pΔV
Gas expands by very small Δx without pressure change
volume change is AΔx
F=pA
W=Fd=pAΔx=pΔV
What does W=pΔV mean for compression or expansion?
If volume decreases, we gain a negative change and a negative value for work done
So work is done on the gas
What is the equation involving pressure and volume for an adiabatic compression?
pV^γ = constant
γ changes on type of gas (diatomic etc)