engineering- thermodynamics Flashcards
what is the Kelvin scale?
the absolute temperature scale
how do you calculate kelvin from degrees celcius?
add 273
what is Boyle’s law?
the pressure of a gas is inversely proportional to the volume
what is Charles’ law?
the volume occupied by a gas is proportional to its absolute temperature
what is the pressure law?
pressure of a gas is proportional to its absolute temperature
what is x?
p ∝ 1/x
V
what is x?
V ∝ x
T (or 1/p)
what law states p ∝ 1/V
Boyle’s law
for the pressure law, what is x?
p ∝ x
T
what is the ideal gas law?
pV = nRT
what equation links number of moles and number of molecules?
number of moles = number of molecules / avogadro’s constant
n = N/ NA
what are 5 assumptions made when modelling an ideal gas?
- its made of tiny spheres
- the spheres obey Newton’s laws of motion
- they occupy a negligible space in comparison with the volume occupied by the gas
- the spheres don’t exert non-contact forces on one another
- collisions involving the spheres are totally elastic
what is the first law of thermodynamics?
Q = ∆U + W
heat energy = internal energy + work done
what is the symbol for heat energy?
Q
what is the symbol for internal energy?
∆U
what is the symbol for work done?
W
which 3 ways can energy change in a closed system?
- heat energy can enter or leave
- work can be done on or by the system
- internal energy store of the system can increase or decrease
what has happened when a system expands?
work is done BY the system
what has happened when temperature decreases?
particles lose energy
when is the value for heat positive?
when heat goes into the system
what happens when work is done on the system?
it is compressed
what is constant during an isothermal process?
∆U = 0
in which non-flow process does the temperature stay the same?
isothermal
what does adiabatic mean?
without the transfer of heat