Energy of reaction Flashcards
Joules
- Units of energy
* In chemistry to make easy comparisons kJ are often used
Endothermic Reaction
• Reaction that overall takes in energy hence will feel colder
•
Exothermic Reaction
Reaction that overall gives out energy hence will feel hot.
Activation energy
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• Minimum energy required to start a reaction.
• Activation energy is endothermic as bonds are broken.
Calorimetry
- Method of measuring energy of a substance that burns by heating water in a glass or metal container.
- Can be used to compare energy in food or fuels
Use equation Q= mass of water x heat capacity x change in Temp
Q = Energy m = Mass of water g (NOT FUEL USED) C= Heat capacity – 4.2 J/C/g (GIVEN) T = Change in temperature - Degree Centigrade
May need calculated energy value into kJ per mole or kJ per gram. = Q/grams or Q/moles
Energy of a chemical reaction in a solution
Measure temperature change in an insulated cup
• Used for dissolving solids in water or neutralisation
Same equation Q= mCAT is used.
What happens in a chemical reaction in terms of energy
- Energy must be supplied to break bonds (endothermic process)
- Energy is released when new bonds are formed (exothermic process)
Energy level diagram
exothermic
Graph with Energy on Y-axis and Progress of reaction on x- axis
Reactants HIGHER than products
Hump line from Reactants to products
Activation arrow must start at reactants and end in line with the peak of the activation energy hump.
Overall energy change arrow must start exactly in line with reactants and end exactly in line with products. (DOWN)
Overall energy is negative as the chemicals have lost energy to the surrounding (hence you feel it get hot).
Energy released from forming new bonds is greater than the energy to break existing bonds.
Energy level diagram
endothermic
Graph with Energy on Y-axis and Progress of reaction on x- axis
Reactants LOWER than products
Hump line from Reactants to products
Activation arrow must start at reactants and end inline with the peak of the activation energy hump.
Overall energy change arrow must start exactly in line with reactants and end exactly in line with products.
Overall energy is positive as the chemicals have gained energy to the surrounding (hence you feel it get cold).
Catalyst
Energy needed to break bonds of the reactants is greater than the energy released by forming new bonds.
Provide an alternative pathway for a chemical reaction that is lower in activation energy.
Activation energy arrow/curve is lower in the energy level diagram.
Hence catalyst speed up the rate of reaction.
Hydrogen (H2)
Hydrogen can be burnt to produce energy e.g.
Hydrogen + oxygen → water
4H2 + O2 → 2H2O
Hydrogen can also be use in fuel cells to produce electricity
Hence can be use to power electrical cars.