energy levels and photon emission Flashcards

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1
Q

how do electrons in atoms exist

A

in discrete energy levels. electrons in an atom can only exist in certain well defined energy levels

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2
Q

what is each level given

A

a number, with n = 1 representing ground state

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3
Q

how can electrons move down energy levels

A

by emitting a photon

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4
Q

what can the value of each photon be

A

these transitions are between definite energy levels so the value can only take a certain allowed value

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5
Q

why is the joule not used

A

the values are so tiny it makes sense to use eV

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6
Q

what is an electron volt defined as

A

the kinetic energy carried by an electron after it has been accelerated through a potential difference of 1 volt

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7
Q

what does 1eV equal

A

1.60 x 10^-19 J

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8
Q

what is the energy carried by each photon equal to

A

the difference in energies between the two levels

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9
Q

show an equation representing transition from a higher energy to a lower energy

A

E(delta) = E2 - E1 = hf = hc/lambda

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10
Q

how can electrons move up energy levels

A

absorbing a photon with the exact energy difference between the two levels

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11
Q

what is the movement of an electron to a higher energy level called

A

excitation

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12
Q

what if an electron is removed from the atom

A

we say the atom is ionised

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13
Q

what is the ionisation energy of an atom

A

the amount of energy needed to completely remove an electron from the atom from the ground state, n = 1

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14
Q

how do fluorescent tubes produce light

A

they use excited electrons

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15
Q

what do fluorescent tubes contain

A

mercury vapor, across which an initial voltage is applied

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16
Q

what does the high voltage do

A

accelerates fast moving free electrons that ionise some of the mercury atoms, producing more free electrons

17
Q

what happens when the flow of mercury atoms collides with electrons in other mercury atoms

A

the electrons in the mercury atoms are excited to higher energy levels

18
Q

what happens next

A

when these electrons return to their ground state, they emit photons in the UV range

19
Q

what absorbs these photons

A

a phosphor coating on the inside of the tube absorbs these photons, exciting its electrons to much higher orbits.

20
Q

what happens next

A

these electrons cascade down to the energy levels emitting many lower energy photons in the form of visible light

21
Q

what do fluorescent tubes also produce

A

line emission spectra

22
Q

how do you get a line spectrum

A

if you split light from a fluorescent tube with a prism or a diffraction grating you get a line spectrum

23
Q

what is a line spectrum seen as

A

a series of bright lines against a black background

24
Q

what does each line correspond to

A

a particular wavelength of light emitted by the source

25
Q

what wavelengths can you see

A

since only certain photon energies are allowed you can only see wavelengths corresponding to these energies

26
Q

what does shining a white light through a cool gas give

A

an absorption spectrum

27
Q

what does a continuous spectra contain

A

all possible wavelengths

28
Q

what is the spectrum of white light

A

continuous

29
Q

what happens if you split the light up with a prism

A

the colours will merge into each other with no gaps in the spectrum

30
Q

what emits a continuous spectrum

A

hot things emit a continuous spectrum in the visible and infrared

31
Q

why are all wavelengths allowed

A

because electrons are not confined to to energy levels in the object. the electrons are not bound by atoms and are free

32
Q

what do cool gases do

A

remove certain wavelengths from a continuous spectrum

33
Q

what do you get when light with a continuous spectrum of energy passes through a cool gas

A

line absorption spectrum

34
Q

where will most of the electrons in a gas atom be in low temperatures

A

ground states

35
Q

what can these electrons absorb

A

only photons with energy equal to the difference between two energy levels

36
Q

what happens to the photons

A

photons of the corresponding wavelengths are absorbed by the electrons to excite them to higher energy levels