Energy Changes and Rates of Reaction Flashcards

1
Q

What are physical reactions?

A

Reactions where a change of state takes place. They are easily reversible, no new substances are formed, and there is no change in mass

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2
Q

What are chemical reactions?

A

Atoms are rearranged. They are not easily reversible. New substances are formed, and substances involved can change mass

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3
Q

What is 0 degrees C in Kelvin?

A

273 Kelvin

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4
Q

What are solids like in terms of particles?

A

Particles are close together in a regular pattern. They do not move but vibrate. There are strong forces between particles, and they do not have much energy

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5
Q

What are liquids like in terms of particles?

A

There is some force between particles. They are close but in a random shape and can move around. They have more energy than solids but less than gases.

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6
Q

What are gases like in terms of particles?

A

There is no force between particles and they can move freely. They have lots of energy and no set shape

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7
Q

What are endothermic reactions?

A

Reactions where substances have more energy than they start with. They take in heat energy.

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8
Q

What are exothermic reactions?

A

Reactions where substances have less energy than they start with. They give out heat energy.

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9
Q

What are examples of endothermic reactions?

A

Thermal decomposition, photosynthesis, some types of electrolysis, cooking

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10
Q

What are examples of exothermic reactions?

A

Combustion, respiration, neutralisation, reactions of metals and acids

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11
Q

What is mexo bendo?

A

Making bonds is EXOthermic, Breaking bonds is ENDOthermic

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12
Q

Why does an exothermic reaction give out heat?

A

Energy is first supplied to break bonds, but then lots of energy is released when bonds are formed

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13
Q

Why does an endothermic reaction take in heat?

A

Some energy is released making bonds, but then lots is supplied breaking bonds

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14
Q

How is overall energy change calculated?

A

Overall energy change = energy required to break bonds - energy released by forming bonds

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15
Q

What is bond enthalpy?

A

The amount of energy needed to make or break a bond

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16
Q

What is rate of reaction?

A

A measure of how fast a reaction happens

17
Q

What things change the rate of reaction?

A

Surface area, concentration or pressure, temperature

18
Q

What is the formula for rate of reaction?

A

Rate of reaction = amount of reactant used or amount of product formed / time

19
Q

How can rate of reaction be calculated?

A

Precipitation (disappearing cross)
Change in mass (from gas given off)
Volume of gas (using a gas syringe)

20
Q

How can you work out the gradient from a curved graph?

A

Draw a tangent (straight line) to the point at which you need to find the gradient and measure its gradient

21
Q

What needs to happen for particles to react?

A

They need to collide with a certain amount of energy or higher

22
Q

What two factors influence rate of reaction?

A

Collision frequency and energy transferred

23
Q

What is the minimum energy particles need to react called?

A

Activation energy

24
Q

How can activation energy be lowered?

A

Using a catalyst