energy changes Flashcards

1
Q

each reactant all has

A

differents amount of chemical energy in their chemical energy store

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2
Q

what is on the y and x axis for a reaction profile diagram

A

the y axis is the energy
the x axis is the progress of the reaction

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3
Q

when the products have less energy than the reactants where is everything placed on the reaction profile and what type of reaction would it be

A

exothermic
1)reactants at the top left starting the graph but not touching y axis

2)products much lower down as they have lost a lot of energy but the start aligning with the end of the reactants

3)straight arrow line drawn down saying energy released

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4
Q

what is an example of exothermic reactions

A

combustion reaction
oxidation
neutralisation(base and acid)

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5
Q

what are examples of exothermic reactions

A
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6
Q

what would the reaction profile for an endothermic reaction look like

A

reactants would be low at the bottom left
products would be high starting at the end of reactants
there would be an up facing arrow drawn for energy absorbed

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7
Q

what is activation energy

A

the minimum amount of energy needed for the reactant particles to collide and react

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8
Q

how does the activation energy link to starting the reaction

A

the higher the activation the more energy required to start the reaction

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9
Q

how can we show the activation energy in the reaction profiles

A

by drawing a curve from products to reactants

the increase in energy from the reactants level to the highest point in our curve is called the activation energy

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10
Q

what is bond energy

A

the amount of energy needed to break one mole (6x10(23)of a particular covalent bond

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11
Q

is bond breaking endothermic or exothermic and why

A

it is endothermic as it requires energy from the surroundings

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12
Q

bond making is

A

exothermic-releases energy to surroundings

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13
Q

what is the equation for energy change

A

energy required to break bonds- energy released by forming bonds

or
energy of reactants - energy of products

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14
Q

what does a - energy change mean

A

the reaction is exothermic
as chemicals lose that value to surroundings

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15
Q

what 3 things happen in a chemical reaction

A

The bonds of the reactant molecules are broken
The atoms rearrange themselves
The bonds of the product molecules are formed

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16
Q

what are electrochemical cells

A

cell made by connecting 2 different electrodes and placing them in contact with an electrolyte all connected to a voltmeter

17
Q

how do batteries compare electrochemical cells

A

they are 2 or more cells connected in series for a greater voltage

18
Q

what 3 factors affect the voltage of a cell

A

-The metals used for the two electrodes. The greater the difference in reactivity of the two metals, the greater the voltage will be.

-The type and concentration of the electrolyte used.

-The conditions, such as temperature.

19
Q

why are rechargable cells/batteries rechargable

A

Rechargeable cells and batteries can be recharged because the chemical reactions are reversed when an external electrical current is supplied. These are the batteries used in laptops and mobile phones.

20
Q

why are non rechargable cells not rechargable

A

chemical reaction stop when 1 reactant has been used up
eg:batteries used in smoke alarms or tv remotes
alkaline batteries are an example

21
Q

why do electrochemical cells have their names

A

converts chemical energy to electrical

a fuel and oxygen into electrical energy which we can use as power

22
Q

what do hydrogen fuel cells do

A

combine hydrogen and oxygen to form water while generating a lot of electrical energy

23
Q

what is the structure of hydrogen oxygen cell

A

electrolyte(commonly potassium hydroxide) in between electrodes with anode (negative)on left and cathode(negative) at top connected by wire at the top

the electrodes are the opposite of electrolysis

24
Q

what do fuel cells have/features

A

electrodes are made of porous carbon with catalyst

they have anode compartment outside electrode with an inlet at the top where hydrogen enters

cathode compartment inlet where oxygen enters

25
Q

when the fuel cell reaction finishes what happens

A

the heat and water leave through the cathode compartment outlet

26
Q

how do fuel cells work

A

hydrogen enters and is oxidised by anode and becomes a hydrogen ion

this equation is
h2—–> 2h+ +2e-

then the electrons flow around wire to the cathode

the hydrogen ions pass the electrode to the cathode

they react with the oxygen that comes in from the cathode inlet combining to make water

27
Q

what is the fuel cell equation at the cathode

A

o2+ 4h+ +4e- ——-> 2h2o

28
Q

when the electrons in a half equation are on the right /left

A

right is loss
left is gain

29
Q

what is the overall equation

A

o2+ 2h2 —>2h2o

30
Q

where does this electrical energy come from in a fuel cell

A

from the movement of electrons through the wire and is powered by the chemical reaction

31
Q

how do fuel cells work

A

as fuel enters cell it gets oxidised setting up pd across cell

32
Q

pros and cons of fuel cells

A

pros
-replace polluting fossil fuel engines and batteries we have in vehicles
-only need hydrogen and oxygen
-no waste pollutants
-simple devices
-last longer than batteries
-less polluting to dispose of

cons
-hydrogen takes up much more space than fossil fuels
-explosive in air
-requires energy to make which often comes from fossil fuels