Energy Changes Flashcards
What is the conservation of energy principle?
Energy is conserved in chemical reactions. The amount of energy in the universe at the end of a chemical reaction is the same as before the reaction takes place.
What is an exothermic reaction? Give examples
A reaction where energy is transferred to the surroundings so that the surroundings temperature increases - combustion, oxidation reactions and neutralisation (acid + alkali) reactions. Negative sign of energy change.
What is an endothermic reaction? Give examples
A reaction where energy is taken in from the surroundings so the surroundings temperature decreases - thermal decomposition, reaction of citric acid and sodium hydrogencarbonate.
Negative sign of energy change.
What is activation energy?
Minimum amount of energy that particles need to react
What is a reaction profile?
Reaction profile is a graph which shows the relative energies of reactants and product, as well as activation energy of the reaction.
What occurs in a chemical reaction in terms of bond energies? Describe exothermic and endothermic reactions in terms of bond breaking/forming.
• Energy is supplied to break bonds and energy is released when bonds are made; exothermic - energy released from forming bonds is greater than that needed to break the bonds; endothermic - energy needed to break bonds is greater than energy released making them
What is the equation to find enthalpy change in terms of bond energies?
Energy of reaction = sum of bonds broken - sum of bonds made
What is a cell?
A cell is composed of two electrodes dipped in an electrolyte solution. It produces electricity from a chemical reaction.
What is a battery?
A battery consists of two or more cells connected in series.
What determines the voltage obtained from a cell?
Identities of metals used as electrodes and the identity and concentration of an electrolyte.
State the advantages and disadvantages of using cells and batteries.
(+) more or less cheap, some are rechargeable, a convenient source of electrical (-) harmful chemicals
Describe rechargeable and non-rechargeable cells
Rechargeable - chemical reactions are reversed when an external current is supplied
Non-rechargeable - reactants are used up, cannot be recharged
What is a fuel cell?
Fuel cells are supplied by fuel and oxygen to oxidise the fuel to generate electricity.
What is the overall reaction in a hydrogen fuel cell? What are the half equations?
Cathode: 2 H2 -> 4 H^+ + 4 e1.
Anode: 02 + 4 H^+ + 4 e1. -> 2 H20
Overall: -> 2 H2 + 02 -> 2 H20
What are the advantages and disadvantages of hydrogen fuel cells?
Advantages: no pollutants, no recharging
Disadvantages: flammable, H2 difficult to store, fossil fuel production, toxic chemicals, expensive production of H2 by electrolysis
What is an exothermic reaction?
An exothermic reaction is one that transfers energy to the surroundings so the temperature of the surroundings increases.
What is an example of an exothermic reaction?
Combustion, many oxidation reactions and neutralisation.
What are everyday uses of exothermic reactions?
Include self-heating cans and hand warmers.
What is an endothermic reaction?
An endothermic reaction is one that takes in energy from the surroundings so the temperature of the surroundings decreases.
What are examples of endothermic reactions?
Endothermic reactions include thermal decompositions and the reaction of citric acid and sodium hydrogencarbonate. Some sports injury packs are based on endothermic reactions.
When do chemical reactions occur?
Chemical reactions can occur only when reacting particles collide with each other and with sufficient energy. The minimum amount of energy that particles must have to react is called the activation energy.
What are reaction profiles used to show?
Reaction profiles can be used to show the relative energies of reactants and products, the activation energy and the overall energy change of a reaction.