Energy and Metabolism Flashcards

1
Q

Define kinetic energy

A

The energy possessed by moving objects

ex. raindrops falling, heart muscles contracting in heartbeat

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2
Q

Define potential energy

A

Stored energy- due to its position within an attractive or repulsive force field (ex. gravitational potential or chemical potential energy)

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3
Q

Define a catabolic reaction

A

The breakdown of complex substances

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4
Q

Define anabolic reactions

A

The build up of complex substances from simpler subunits

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5
Q

Define metabolism

A

The sum of all anabolic and catabolic processes (chemical reactions) in a cell or organism

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6
Q

Define the first law of thermodynamics

A

Principle that states the total amount of energy is in the universe is constant- energy cannot be created or destroyed but only converted from one form to another
- if an object has energy it does at the expense of loss of energy elsewhere

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7
Q

Define bond energy

A

The minimum energy required to break one mole of bonds between two types atoms
- equal to the amount of energy released when a bond forms

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8
Q

Is energy added or released when a bond is broken?

A

Added

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9
Q

Is energy added or released when a bond is created?

A

Released

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10
Q

Define activation energy

A

The amount of energy required to strain and break the reactants’ bonds
- to start a chemical reaction

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11
Q

What is activation energy equal to?

A

The difference between the potential energy level of the transition stage and the reactants

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12
Q

Define the transition state

A

Temporary condition in which the bonds within reactants are breaking and bonds between products are forming

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13
Q

Define an exothermic reaction

A

A chemical reaction in which energy is absorbed, giving the products more chemical potential energy than the reactants
- negative H value

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14
Q

Define an endothermic reaction

A

A chemical reaction in which energy is absorbed, giving the products more chemical potential energy than reactants
- positive H value

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15
Q

Define work

A

The ability to apply a force to move an object

- examples are breathing,

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16
Q

Define the second law of thermodynamics

A

In every energy transfer or conversion, some of the useful energy in the system becomes unstable and increases the entropy of the universe

17
Q

Define entropy

A

The degree of disorder in a measurable quantity

18
Q

Do all systems in the universe tend toward order or disorder?

A

Disorder

19
Q

What causes an increase in entropy?

A

Any change, such as a chemical reaction

20
Q

When does entropy increase in chemical reactions?

A
  • solids react to form liquids or gasses
  • liquids react to form gaseous products
  • the total number of product molecules is greater than the total number of reactant molecules
21
Q

Do living organisms defy the second law of thermodynamics?

A

No, energy can be expanded to establish and maintain order

- there is a greater increase in entropy in the universe than there is a decrease of entropy in the organism

22
Q

Define a spontaneous change

A

A change that once started will proceed to completion without any input of energy
- ex lighting a match, burning paper, melting ice above 0

23
Q

Are spontaneous changes catabolic or anabolic?

A

Catabolic

24
Q

Define a non-spontaneous change

A

A change that once started, will not go to completion unless a constant supply of energy is input
- ex water melting at -10 degrees

25
Q

Are non-spontaneous reactions catabolic or anabolic?

A

Anabolic

26
Q

What is responsible for the chemical and physical work in living organisms?

A

Free energy

27
Q

Equation of change in free energy

A

G final equation- G initial equation

28
Q

What does a negative change in free energy mean?

A

Free energy of products is less than free energy of reactants

29
Q

What does positive change in free energy mean?

A

Products have more free energy than the reactants

30
Q

Do reactions with negative change in free energy occur spontaneously? Do they gain or give off energy?

A

Yes, give off free energy

31
Q

Do reactions with positive change in free energy occur spontaneously? Do they gain or release energy?

A

No, they occur non spontaneously and must gain energy from an external source

32
Q

When is an exothermic reaction spontaneous with an increase in entropy?

A

Spontaneous at all temps

- burning wood, cellular respiration

33
Q

When is an exothermic reaction spontaneous with an decrease in entropy?`

A

Spontaneous at low temps only

- water freezing

34
Q

When is an endothermic reaction spontaneous with an increase in entropy?

A

Spontaneous at high temps only

Ex. Ice melting

35
Q

When is an endothermic reaction spontaneous with an decrease in entropy?

A

Not spontaneous at any temp

- formation of diamonds or glucose

36
Q

Define free energy

A

The energy that is not lost, and can perform work in the body

37
Q

Describe Gibbs free energy in non/spontaneous reactions

A

Free energy released in spontaneous changes

Free energy absorbed in non spontaneous changes

38
Q

Describe an exergonic reaction

A
  • catabolic
  • spontaneous
  • release free energy
  • useful energy
  • negative value
39
Q

Describe an endergonic reaction

A
  • anabolic
  • not spontaneous
  • require free energy
  • positive value