Energy and Metabolism Flashcards

1
Q

Define kinetic energy

A

The energy possessed by moving objects

ex. raindrops falling, heart muscles contracting in heartbeat

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2
Q

Define potential energy

A

Stored energy- due to its position within an attractive or repulsive force field (ex. gravitational potential or chemical potential energy)

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3
Q

Define a catabolic reaction

A

The breakdown of complex substances

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4
Q

Define anabolic reactions

A

The build up of complex substances from simpler subunits

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5
Q

Define metabolism

A

The sum of all anabolic and catabolic processes (chemical reactions) in a cell or organism

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6
Q

Define the first law of thermodynamics

A

Principle that states the total amount of energy is in the universe is constant- energy cannot be created or destroyed but only converted from one form to another
- if an object has energy it does at the expense of loss of energy elsewhere

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7
Q

Define bond energy

A

The minimum energy required to break one mole of bonds between two types atoms
- equal to the amount of energy released when a bond forms

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8
Q

Is energy added or released when a bond is broken?

A

Added

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9
Q

Is energy added or released when a bond is created?

A

Released

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10
Q

Define activation energy

A

The amount of energy required to strain and break the reactants’ bonds
- to start a chemical reaction

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11
Q

What is activation energy equal to?

A

The difference between the potential energy level of the transition stage and the reactants

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12
Q

Define the transition state

A

Temporary condition in which the bonds within reactants are breaking and bonds between products are forming

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13
Q

Define an exothermic reaction

A

A chemical reaction in which energy is absorbed, giving the products more chemical potential energy than the reactants
- negative H value

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14
Q

Define an endothermic reaction

A

A chemical reaction in which energy is absorbed, giving the products more chemical potential energy than reactants
- positive H value

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15
Q

Define work

A

The ability to apply a force to move an object

- examples are breathing,

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16
Q

Define the second law of thermodynamics

A

In every energy transfer or conversion, some of the useful energy in the system becomes unstable and increases the entropy of the universe

17
Q

Define entropy

A

The degree of disorder in a measurable quantity

18
Q

Do all systems in the universe tend toward order or disorder?

19
Q

What causes an increase in entropy?

A

Any change, such as a chemical reaction

20
Q

When does entropy increase in chemical reactions?

A
  • solids react to form liquids or gasses
  • liquids react to form gaseous products
  • the total number of product molecules is greater than the total number of reactant molecules
21
Q

Do living organisms defy the second law of thermodynamics?

A

No, energy can be expanded to establish and maintain order

- there is a greater increase in entropy in the universe than there is a decrease of entropy in the organism

22
Q

Define a spontaneous change

A

A change that once started will proceed to completion without any input of energy
- ex lighting a match, burning paper, melting ice above 0

23
Q

Are spontaneous changes catabolic or anabolic?

24
Q

Define a non-spontaneous change

A

A change that once started, will not go to completion unless a constant supply of energy is input
- ex water melting at -10 degrees

25
Are non-spontaneous reactions catabolic or anabolic?
Anabolic
26
What is responsible for the chemical and physical work in living organisms?
Free energy
27
Equation of change in free energy
G final equation- G initial equation
28
What does a negative change in free energy mean?
Free energy of products is less than free energy of reactants
29
What does positive change in free energy mean?
Products have more free energy than the reactants
30
Do reactions with negative change in free energy occur spontaneously? Do they gain or give off energy?
Yes, give off free energy
31
Do reactions with positive change in free energy occur spontaneously? Do they gain or release energy?
No, they occur non spontaneously and must gain energy from an external source
32
When is an exothermic reaction spontaneous with an increase in entropy?
Spontaneous at all temps | - burning wood, cellular respiration
33
When is an exothermic reaction spontaneous with an decrease in entropy?`
Spontaneous at low temps only | - water freezing
34
When is an endothermic reaction spontaneous with an increase in entropy?
Spontaneous at high temps only | Ex. Ice melting
35
When is an endothermic reaction spontaneous with an decrease in entropy?
Not spontaneous at any temp | - formation of diamonds or glucose
36
Define free energy
The energy that is not lost, and can perform work in the body
37
Describe Gibbs free energy in non/spontaneous reactions
Free energy released in spontaneous changes | Free energy absorbed in non spontaneous changes
38
Describe an exergonic reaction
- catabolic - spontaneous - release free energy - useful energy - negative value
39
Describe an endergonic reaction
- anabolic - not spontaneous - require free energy - positive value