Energy And Equlibrium Flashcards

1
Q

What happens when bonds are broken?

A

Energy is taken is in

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2
Q

What happens when bonds are formed?

A

Heat energy is given out

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3
Q

What is an exothermic reaction?

A

A chemical reaction that gives out heat energy

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4
Q

What is an endothermic reaction?

A

A chemical reaction that takes in heat energy

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5
Q

Examples of exothermic reactions are?

A

Neutralisation
Combustion
Displacement reactions
Dissolving
Hydration

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6
Q

Examples sod endothermic reactions are?

A

Thermal decomposition
Photosynthesis
Dissolving
Electrolysis
Thermal cracking of hydrocarbons

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7
Q

Explain how the energy within an exothermic reaction changes as the reaction progresses and how it looks on a graph.

A

Look in book
The products are below the reactants as they have less energy

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8
Q

Explain how the energy within an endothermic reaction changes as the reaction progresses and how it looks on a graph.

A

Look in book
The Products are above the reactants as they have more energy

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9
Q

How do you calculate energy change in a chemical reaction?

A

Energy change = Energy taken in to break bonds - Energy released when new bonds are formed

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10
Q

What is the definition of reversible?

A

A reaction which goes in both the forward and backward directions

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11
Q

What is the definition of dynamic equilibrium?

A

The rate of the forward reaction is equal to the rate of the backward reaction and the amounts of reactant and product remain constant

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12
Q

What is the definition of homogeneous?

A

A reaction in which all the reactants and produce that are produced are in the same physical state

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13
Q

What is Le Chatlier’s principle?

A

If a dynamic equilibrium is distributed by changing the conditions, the position of equilibrium moves to counteract the change.

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14
Q

What is the affects of changing the pressure in a closed homogenous system?

A

If more of a chemical is added the equilibrium position moves to remove it

If some of a chemical is removed, the equilibrium position moves to make more of it

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15
Q

What are the affects of changing the pressure in a closed homogeneous system?

A

To increase the pressure, the position of the equilibrium moves to the side with the most gas molecules and vice versa to decrease the pressure

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16
Q

What are the affects of changing the temperature in a closed homogeneous system?

A

Increasing the temperature of a system in dynamic equilibrium favours the endothermic reaction as it counteracts the change by absorbing more heat

Decreasing the temperature of a system in dynamic equilibrium favours the exothermic reaction as it counteracts the change by producing more heat

17
Q

What is a closed system?

A

Where no substances can get in or out

18
Q

What is the Haber process?

A

Combines nitrogen from the air with hydrogen derived mainly from natural gas (methane) into ammonia.

The reaction is reversible and exothermic

19
Q

What are the industrial conditions for the haber process?

A
  • 200 atmospheres of pressure
  • 450 degrees centigrade
  • Iron catalyst
20
Q

What are the raw materials for the have process?

A

Hydrogen - obtained by reacting natural gas (methane) with steam, or through the cracking of oil

Nitrogen - Obtained by burning hydrogen in air

21
Q

How is nitrogen obtained?

A

Air is 78% nitrogen nearly all the rest is oxygen. When hydrogen is burned in air the oxygen combines with hydrogen, leaving nitrogen behind.