Energy Flashcards

1
Q

Thermodynamics

A
  • The study of energy transfer that we can measure in the macroscopic words
  • Does not make any assumptions about the microscopic world (like KMT)
  • Heat transfers until thermal equilibrium is established
  • ΔT measures energy transfer
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2
Q

Energy

A
  • The capacity to do work or produce heat
  • Most energy can be exchanged between objects through contact
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3
Q

Work

A

Form of energy based on moving an object over a distance

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4
Q

Heat

A
  • The form of energy that flows betweem 2 objects because of their difference in temperature
  • Quantity of hotness (mass + speed)
  • Thermal energy
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5
Q

Temperature

A

Average kinetic energy

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6
Q

What is a calorie

A
  • heat required to raise ttemp of 1.00 g of H2O by 1.0 °C
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7
Q

Units of energy

  • cal –> kcal
  • kcal –> Cal
  • cal –> joules
A
  • 1000 cal = 1 kcal
  • 1 kcal = 1 Calorie (a food “calorie”)
  • 1 cal = 4.184 joules
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8
Q

First law of thermodynamics

A

The total energy content of the univerws is constant

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9
Q

Potential energy

A

Stored energy that an object has by virtue of its position or compsotion

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10
Q

Kinetic energy

A

energy of motion or energy of a reaction

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11
Q

5 forms of energy (PE or KE)

A
  1. Electrical - KE
  2. Heat / thermal energy - KE
  3. Light / radiant energy - KE
  4. Nuclear - PE
  5. Chemical - PE
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12
Q

Internal energy

A
  • sum of all forms of KE (motion of atoms/molecules) and PE (rep by tthe chemical bonds and IMFs) in a system
  • E = internal energy
  • E = PE + KE
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13
Q

System

A

The object under study

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14
Q

Surroundings

A

Everything outside the system

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15
Q

Direcionality of heat transfer

A
  • Heat always transfers from hoter objec to cooler one
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16
Q

Exothermic reaction

A
  • heat transfers from system to surroundings
  • PE of products < PE of reactants
17
Q

Endothermic reaction

A
  • heat transfers from surroundings to system
  • PE of products > PE of reactants
18
Q

Change in energy equation

A
  • ΔE = q + w
  • change in energy = heat + work
  • if isolated system (closed) then ΔE of system = 0
19
Q

q, w, ΔE signs (+ or -)

A
  • +q: system gains energy
  • -q: system releases heat
  • +w: system gains energy from work (compression)
  • -w: system releases energy by doing work (expansion)
  • +ΔE: system gains energy
  • -ΔE: system releases energy
20
Q

work equation

A
  • w = -PΔV
  • constant pressure
21
Q

Heat capacity (c)

A
  • The heat required to raise an object’s temp by 1 C
  • Cup vs tub: tub has higher heatt capacity
22
Q

Specific heat

A
  • The amount of heat required to raise the temp of one gram of a substance by one degree celsius
  • H2O: 4.184 J / gºC
  • How much energy is tranferred due to temp difference?
  • The heat (q) lost or gained is related to
    • sample mass
    • change in T
    • specific heat capacity
23
Q

specific heat equation: q=

A

q = smΔT

24
Q

Calorimetry

A
  • The amount of heat absorbed or released during a physical or chemical change can be measured, usually by the change in temp of a known quantity of water in a calorimeter
25
Q

Enthalpy

A
  • A state function that accounts for heat flow in the processes (chemical or physical) that occurs at constant pressure when no forms of work are performed except P-V work
  • No gas, no change in volume
  • H = ΔE + PΔV
  • ΔH = q (at constant P)
  • For a chemical reaction:
    • ΔH = Hproducts - Hreactants
26
Q

State function

A
  • A property that is independent of the pathway
  • Enthalpy
  • Temperature
  • Energy
27
Q

Not state functions

A
  • Heat and work
28
Q

Rate

A

change in property / time

29
Q

3 things must happen to molecules in order for a reaction to occur

A
  • Collide
  • Energy to react (have to collide with enough force)
  • Orientation
30
Q

Activated complex

A

Top of hill on energy diagram

31
Q

Rate determining step

A

Slowest reaction is the RDS

32
Q

Exothermic fast vs slow reaction

A
  • Fast: small upward hill
  • Slow: large upward hill