energetics Flashcards

1
Q

what does system mean in a chem reaction

A

the atoms and bonds involved in the chem reaction

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1
Q

what does system mean in a chem reaction

A

the atoms and bonds involved in the chem reaction

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2
Q

law of conservation

A

amount of energy in an isolated system remains the same.
energy cannot be destroyed or created.
can only be transferred from one form to another

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3
Q

what energy change is breaking bonds associated with

A

endothermic- energy is taken in

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4
Q

what energy change is making bonds associated with

A

exothermic- energy is released to make bonds

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5
Q

activation energy

A

minimum energy required for a reaction to take place

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6
Q

standard T

A

298K
20 *C

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7
Q

standard P

A

100kPa

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8
Q

define enthalpy (H)

A

total energy contents of the reacting materials

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9
Q

define enthalpy change

A

describe energy exchange that takes place with surroundings under standard conditions

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10
Q

unit of enthalpy change

A

kJmol

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11
Q

exothermic

A

energy released on bond formation in the products is greater than absorbed by breaking the bonds in reactants

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12
Q

examples of exothermic reactions

A

combustion
neutralisation
metal displacement

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13
Q

endothermic

A

energy needed to be absorbed to break bonds in the reactants is greater than the energy transferred to surroundings as bonds are made in products

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14
Q

examples of endothermic

A

photosynthesis
thermal decomposition
cracking

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15
Q

4 types of standard enthalpy change

A

reaction
formation
combustion
neutralisation

16
Q

define reaction standard enthalpy change

A

energy transferred when the molar quantities of reactants react under standard conditions

17
Q

define formation standard enthalpy change

A

1 mol of a product is formed from its elements under standard states and conditions

18
Q

example of formation SEC

A

H2 + 1/2 O2 -> H2O(l)

19
Q

what is the enthalpy change of a formation of an element always

A

0 kJmol

20
Q

define combustion standard enthalpy change

A

one mol of a substance burns completely in oxygen under standard conditions. must only be one mol of the fuel/reactant.

21
Q

is combustion endothermic or exothermic

A

exothermic

21
Q

is combustion endothermic or exothermic

A

exothermic

22
Q

which type of standard enthalpy change always produces one mol of product

A

formation

23
Q

which type of standard enthalpy change always uses 1 mol of reactant

A

combustion

24
Q

which type of standard enthalpy change always uses 1 mol of reactant

A

combustion

24
Q

which type of standard enthalpy change always produces one mol of water

A

neutralisation

25
Q

define neutralisation standard enthalpy change

A

energy change when acid and alkali in an equation for reaction neutralise eachother under standard conditions to form one mol of water

26
Q

what is the standard enthalpy change of neutralisation if a strong acid is used

A

-57 kJmol

27
Q

what is the standard enthalpy change of neutralisation if a weak acid is used

A

-55/56 kJmol

28
Q

what is the symbol for standard enthalpy change of neutralisation

A

△ₙH⦵

29
Q

what is the symbol for standard enthalpy change of formation

A

△ᶠH⦵

30
Q

what is the symbol for standard enthalpy change of combustion

A

△ᶜH⦵

30
Q

what is the symbol for standard enthalpy change of reaction

A

△ᵣH⦵

31
Q

equation to find amount of energy (q), step 1 in calculating enthalpy change

A

q=mc△T

32
Q

equation to find enthalpy change △H

A

△H=q/n

33
Q

what assumption do we make when using q=mc△T

A

we assume that 4.18 (SHC of water) is the SHC of a solution