EN 13211 - Mercury Flashcards

1
Q

Name the 2 normative references in EN 13211

EN 13211 - Mercury

A

EN 1483 - water quality
EN 13284-1 - total particulate matter

EN 13211 - Mercury

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2
Q

What is the concentration range for EN 13211?

EN 13211 - Mercury

A

0.001 to 0.5 mg/m³

EN 13211 - Mercury

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3
Q

What is the acceptable concentration of mercury present in the last impinger?
(2 things)

EN 13211 - Mercury

A

< 5% of the total in all the impingers OR < 2 ug/m³

EN 13211 - Mercury

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4
Q

Name the 3 conditions for when non-isokinetic sampling can be employed?

EN 13211 - Mercury

A
  1. If the sum of the mercury in the dust phase is < 1 µg/m³ &
  2. No droplets are present in the gas stream &
  3. The highest to lowest velocity ratio is < 1.2

EN 13211 - Mercury

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5
Q

What is the maximum permissible mercury content of the filter?

EN 13211 - Mercury

A

< 0.1 µg/m³ (Quartz Fibre)

EN 13211 - Mercury

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6
Q

What is permissible length of an unheated connection?

EN 13211 - Mercury

A

< 1m

EN 13211 - Mercury

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7
Q

Which 2 impinger solutions are permitted?

EN 13211 - Mercury

A
  1. Potassium permanaganate in sulphuric acid
  2. Potassium dichromate in nitric acid

EN 13211 - Mercury

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8
Q

What temperature should the samples be stored at?

EN 13211 - Mercury

A

Standard requires < 6°, RPS allows < 25°C

EN 13211 - Mercury

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9
Q

How should the filters be digested post-test?

EN 13211 - Mercury

A

In a closed PTFE vessel at elevated temperature and pressure using nitric acid and hydrofluoric acid

EN 13211 - Mercury

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10
Q

What 3 conditions must be satisifed to enable single point sampling?

EN 13211 - Mercury

A
  1. Standard deviation in velocities of < 10% of the mean
  2. Variation in temperature of < 10°C
  3. Standard deviation in oxygen concentration of < 10% of the mean

EN 13211 - Mercury

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11
Q

What must the probe temperature be set to if titanium is present in the sampling train?

EN 13211 - Mercury

A

> 180°C

EN 13211 - Mercury

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12
Q

What typical flow rate is suggested in the Standard?

EN 13211 - Mercury

A

1.0 to 2.0 m³/hr (16 to 33 l/min)

EN 13211 - Mercury

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13
Q

What is the allowable leak?

EN 13211 - Mercury

A

< 2% of expected sample flow

EN 13211 - Mercury

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14
Q

What is the valid isokinetic range?

EN 13211 - Mercury

A

95 to 115%

EN 13211 - Mercury

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15
Q

What is the allowable absorption efficiency?

EN 13211 - Mercury

A

> 95%. Efficiency not required if the emissions are ≤ 30% of the daily ELV

EN 13211 - Mercury

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16
Q

What shall the measurement uncertainty value at the daily ELV not exceed?

EN 13211 - Mercury

A

± 30% on a dry gas basis before correction to oxygen

EN 13211 - Mercury

17
Q

What rinse solution is used?

EN 13211 - Mercury

A

5% Nitric acid

EN 13211 - Mercury

18
Q

How many days must the sample be analysed in?

EN 13211 - Mercury

A

14 days from birth

EN 13211 - Mercury

19
Q

How many and when must a blank be taken?

EN 13211 - Mercury

A

One per sampling location per day

EN 13211 - Mercury