Electrons, Bonding and structure module 2.2 Flashcards
ionic bonding
electrostatic attraction between positive and negative ions
explain the solid structure of giant ionic lattices
the oppositely charged ions surrounding each ion attracts each other from all directions forming a giant ionic lattice
explain why ionic compound have a high melting and boiling point
because a large amount of energy is needed to break the strong electrostatic bonds that hold the oppositely charged ions in the giant lattice.
why does MgO have a higher melting point than NaCL?
Because Mgo has a greater charge and the greater the charge the stronger the electrostatic forces between the ions.
explain the conductivity of a ionic compound in solid and molten state
in a solid the ions are held in a fixed position and no ions can move so they can’t carry the electrical current therefore it does not conduct electricity. When molten the ions are free to move so can conduct electricity.
describe the solubility of ionic compounds?
they dissolve is polar solvents as they break down the ionic lattice by surrounding each ion. the slight charges within the polar substances attract to the charged ions in the giant ionic lattice meaning the structure is disrupted and ions are pulled out of it
why does solubility decrease as the charges of the ions increases
the polar substance cannot overcome tthe electrostatic forces of attraction
covalent bonding
the strong electrostatic attraction between shared pair of electrons and the nuclei of the bonded atom
why are some elements able to have 10 electrons in there outer shell when they form a covalent bond?
because they have a 3d subshell so are able to have a maximum of 18 in there outer shell. this is called expansion of the octect
average bond empathy
a measurement of covalent bond strength
CH4 angle
109.5
NH3 angle
107
H20 angle
104.5
Factors electronegativity depends on
- the size of the positive charge on the nucleus. The more protons in the nucleus the higher the charge
- the atomic radius, the smaller the atomic radius the closer the bonding electrons will be be to the nucleus of an atom so the more electronegativity
- shielding of the nucleus by inner shells
What causes induced dipole-diploma infractions ?
Random movement of electrons which unbalances the distribution of charge within the electron shells. The instantaneous dipole is