Electrons, Bonding and Structure full module Flashcards

1
Q

What are electron shells made up of?

A

Sub-shells and orbitals

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2
Q

What do electrons move around the nucleus in?

A

shells (energy levels)

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3
Q

What is the name of the number given to shells?

A

Principle quantum number

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4
Q

What are shells divided into and what are there 4 names

A

Subshells, S P D and F

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5
Q

What does each subshell have a different number of?

A

orbitals

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6
Q

How many electrons can fit into 1 orbital?

A

2

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7
Q

How many orbitals does the S and P subshell have speperatly?

A

S:1 P:3

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8
Q

What shape is the S orbitall?

A

spherical

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9
Q

What shape is the P orbital?

A

Dumbell

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10
Q

what is the electron configuration of potassium (K) (19e’s)

A

1s2 2s2 2p6 3s2 3p6 4s1

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11
Q

How are ions formed?

A

When electrons are transferred from one atom to another so as to have a full outer shell, they can be positively or negatively charged.

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12
Q

What holds ions together?

A

electrostatic attraction

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13
Q

What is an ionic bond?

A

an electrostatic attraction between two oppositly charged ions

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14
Q

What diagram shows ionic bonding?

A

dot and cross diagrams

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15
Q

Do ionically bonded substances conduct electrisity? why

A

Yes when molten or dissolved as the ions can move and carry a charge

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16
Q

What type of mp and bp do ionic comounds have? why

A

High as the giant ionic lattices are held together by strong electrosatic forces that take lots of energy to overcome.

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17
Q

Why do ionic compunds dissolve?

A

As water is polar so part of the molecule is attracted the the water and part of it pull it away causing it to dissolve

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18
Q

What are molecules nd what holds them together?

A

they are two or more atoms covalently bonded together

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19
Q

what is covalent bonding?

A

The strong electrostatic attraction between a shared pair of electrons and the nuclei of bonded atoms

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20
Q

What is dative covalent bonding?

A

When both electrons in a bond come from one atom

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21
Q

What repels more bonded pairs or lone pairs?

A

lone pairs

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22
Q

In molecule shapes where is the greatest angle

A

between lone pairs

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23
Q

If a molecule has 2 bonded pairs and 0 lone pair what is the bond angle and shape of the molecule?

A

linear 180

24
Q

if a molecule has 3 bonded pairs and 0 lone pair what is the bond angle and shape of the molecule?

A

trigonal planar 120

25
if a molecule has 3 bonded pairs and 1 lone pair what is the bond angle and shape of the molecule?
bent and angle<120
26
if a molecule has 4 bonded pairs and 0 lone pair what is the bond angle and shape of the molecule?
tetrahedral 109.5
27
if a molecule has 4 bonded pairs and 1 lone pair what is the bond angle and shape of the molecule?
pyramidal angle<109.5
28
if a molecule has 4 bonded pairs and 2 lone pair what is the bond angle and shape of the molecule?
bent angle<109.5
29
if a molecule has 5 bonded pairs and 0 lone pair what is the shape of the molecule?
trigonal bipyramidal
30
if a molecule has 6 bonded pairs and 0 lone pair what is the bond angle and shape of the molecule?
octahedral 90
31
what is electronegativity
an atom's ability to attract the electron pair in a covalent bond
32
what is the most electronegative molecule and the top 3 after
Flourine then oxygen, nitrogen and chlorine
33
What is electronegativity measured in?
the pauling scale
34
why may a covalent bond be polarised?
difference in electronegativity
35
How is a bond polar/
between two atoms of different electronegativity when the bonding electrons are pulled towards the more electronegative atom
36
What is a dipole?
a shift in electron density in a bond
37
What is caused by a polar bond?
a permanent dipole
38
What makes a bond more polar?
a greater difference in electron density
39
Give an example of when a covalent bond is non polar?
between diatomic gases eg H2 Cl2
40
How is charge arranged in polar molecules?
unevelenly
41
What happens if polar bonds are arranged symmetrically
The dipoles cancel out and the bond is non-polar an example is carbon dioxide
42
What bonds are truely covalent?
Only those between a single element.
43
How can you use electronegativity to predict what type of bond will occur between 2 atoms?
The higher the difference in electronegativity the more ionic it becomes
44
How strong are intermolecular forces?
Very weak. weaker than all types of bonding
45
Are all compounds covalent or ionic?
No, most compunds are inbetween ionic and covalent
46
what are the 3 intermolecular forces?
1. Induced dipole-dipole forces (Lodnon forces) 2. Permanent dipole-dipole interations 3.Hydrogen bonding
47
What is induced dipole-dipole forces (London forces)?
Electrons in a charged cloud are always moving, any any particular moment they are more likely to be on one side of an atom then the other. This causes a tempory dipole.
48
What atoms do induced dipole-dipole forces happen in
All atoms even noble gases
49
What can induced dipole-dipole forces cause?
A neighbouring atom to experience another induced dipole in the opposite direction, this causes a chain of dipoles in atoms near eachover.
50
What does the stronger induced dipole dipole forces cause? and why?
Higher bp and mp. Because the larger electron cloud has more intermolecular forces which need to be broken in order to boil a substance.
51
What are permanent dipole-dipole interations?
Slightly negative and positive charges on polar molecules causing weak electrostatic forces of attraction between molecules.
52
What is the strongest intermolecular force?
Hydrogen bonding
53
What can hydrogen bonding occur between?
Hydrogen and Flourine, Nitrogen or Oxygen.
54
Why does hydrogen bond to Floruine (or oxygen or nitrogen)
as hydrgoen has a high charge density because it is so small and flourine is very electronegative. The bond is so polarised that a weak bond between the hydrogen of one molecule and a long pair of electrons on the flourine in another molecule.
55
When drawing molecules what does a straight line show us?
The bonds and their atoms lie on the plane of the page
56
When drawing molecules what does a solid wedge show us?
The bond and its atom is coming out of the plane of the page
57