Electronegatvity & Polarity Flashcards
What is electronegativity?
The power of an atom to attract the bonding pair of electrons in a covalent bond.
How does electronegativity change throughout the periodic table?
- increases across periods
- increases up the group
What is the difference in electronegativity in a covalent bond?
0
What is the difference in electronegativity in a polar covalent bond?
0 to 1.8
What is the difference in electronegativity in an ionic bond?
Greater than 1.8
What is a non-polar bond?
Bonded electron pair is shared equally between the bonded atoms
—> atoms are the same
—> atoms have the same or similar electronegativity
What is a polar bond?
Bonded electron pair is shared unequally between the bonded atoms.
—> atoms are different
—> atoms have different electronegativity values
What type of dipole is present in a polar covalent bond?
Permanent dipole as it does not change
Which shaped molecules have an overall dipole?
Non-symmetrical (pyramidal, non-linear)
Which shaped molecules have no overall dipole?
Symmetrical (linear, trigonal planar, tetrahedral, octahedral)
How do polar solvents dissolve giant ionic lattice’s?
- water molecules surround the ions
- +ve ions are attracted to slightly -ve molecules
- -ve ions are attracted to slightly +ve molecules
- so the ionic lattice breaks down as it dissolves