Electronegatives and Bonding Flashcards
Ionic Bonds
Difference in electronegativity is greater than 1.6
ex.
Na F
0.9 4.0
3.1 ( 4.0-0.9= 3.1)
3.1 is greater than 1.6, so this is a Ionic Bond
Covalent Bonds
Difference in electronegativity is less than 0.2
ex.
Cl2
Cl Cl
3.0 3.0
0
0 is less than 0.2, so this is a Covalent Bond
Polar Covalent Bonds
Difference in electronegativity is between 0.2 and 1.6
ex.
Ca Se
1.0 2.4
1.4
1.4 is in between 0.2 and 1.6, so this is a Polar Covalent Bond
Dipole
The partial charge on atoms within a neutral molecule
Molecules
Can be Polar or Non-Polar
Polar- Dipoles exist and don’t cancel out
ex. BrFeCl
Br-Fe-Cl 2.8 1.8 3.0 1.0 1.2 Polar Molecule (dipoles aren't equal) Non-Polar- No dipoles or they cancel each other out ex. FeCl2 Cl-Fe-Cl 1.2 1.2 0.2<1.2<1.6 Non Polar Molecule (equal dipoles)
Steps
- Draw structure of molecule
- Determine dipoles within the molecule
- Determine if dipoles cancel
Equal Bond Angles
ex. FeCl3 Fe-Cl 1.8 3.0 1.2
Cl Fe Cl Cl Dipoles would go towards the Cl because it is more electronegative
Water
H2O O H H H-O 2.1 3.5 1.4 H2O is a Polar Molecule
What dissolves in Water?
Polar and ionic substances
What dissolves in hexane?
Non-Polar substances