Electron Structure Flashcards
What is the maximum amount of electrons that can go into each main shell and what are their energy levels?
1- 2 electrons lowest energy
2- 8 electrons
3- 18 electrons
4- 32 electrons highest energy
What are shells made up from?
Orbitals
How many electrons can 1 orbital hold?
2 electrons
What are the 3 different types of orbitals what shape do they have, how many are there in each sub-shell and what is the max amount of electrons they hold?
s orbital- spherical shape
Each sub-level has 1 s orbital
Each s orbital holds 2 electrons
p orbital- dumbbell shape
Each sub-level after level 1 has 3 p orbitals
Each p orbital holds 2 electrons so in each subshell (3x2) holds 6 electrons
d orbital
Each sub-level after 3 has 5 d orbitals
Each d orbital holds 2 electrons so in each subshell (5x2) holds 10 electrons
For each main shell name the type and number of each orbitals, the max number of electrons from each type of orbital and the max number of electrons in that shell:
1- 1s which holds 2 electrons therefore max number is 2
2- 1s 3p (2+6) so max number is 8
3- 1p 3p 5d (2+6+10) so max number is 18
What is spin and how is it represented?
The property of electrons due to them repelling as they have a negative charge
Up and down arrows represent spin
What is an orbital?
The space around the nucleus that can hold up to 2 electrons of opposite spin
How is electron configuration written?
E.g 3p^6
3 (large number) represents the number of the main shell
p (the letter) represents type of orbital
^6 (the power) represents how many electrons in the sub-shell
Written in order of energy level
Why is 4s written before 3d?
4s has a lower energy level than 3d so is filled 1st
What are the rules for filling shells and sub-shells?
- Electrons added 1 at a time
- Lowest available energy level fills 1st
- Each main shell (usually) is full before the next one starts to fill
- In p+d orbitals each orbital fills singly before pairing
- Electrons in each orbital have opposite spin
What are the 2 exceptions to these rules and why?
Chromium and copper-
Half-filled and full subshells are more stable so 1 of the electrons from 4s is moved to 3d leaving -
Cr- 4s^1 3d^5
Cu- 4s^1 3d^10
In the periodic table what does the block of an element represent?
The highest energy sub-shell occupied by an electron
What is the periodic trend in electron configuration across a period?
Each period starts with an electron in the newest highest energy main shell
Across the period the s+p sub shell are filled the same way (repeating pattern)
What is the periodic trend in electron configuration down a group?
Elements in the same group have the same number of electrons in outer shell and same number of electrons in each outer sub-shell
How are positive cations formed and how does the electron configuration change from atom to ion?
Formed when electrons are removed (from highest energy sub-shell 1st)
Electron configuration is shortened as electrons are removed