Electron Configuration Exceptions and more definitions Flashcards
Aufbau Principle
electrons fill orbitals from ground up, electrons must be at the lowest possible energy level
energy-level diagrams
Relative energies of the electrons in an atom
Hund’s Rule
electrons fill orbitals where no pairs are put into orbitals unless necessary, they will first occupy empty orbitals b4 pairing
Pauli Exclusion Principle
unpaired electrons have parallel spins, and no 2 electrons in an atom have the same quantum numbers
What are the 2 exceptions to the Aufbau Principle?
Electron configuration of Chromium and Copper (would also happen to Molybdenum, below Chromium)
Why?
- unfilled substances are less stable than half and fully filled substances
- unfilled substances have greater energy
In the case of Copper, its more stable for the electron in 3d to move to 4s which goes against the Aufbau principle
REVIEW: WHY IS COPPER AN EXCEPTION TO THE AUFBAU PRINCIPLE
Copper is an exception because a filled “d” sub shell is more stable than a full “s”, therefore, an electron moves from the “s” sub shell to the “d” sub shell
THEREFORE, IF THERE IS A FULL S BLOCK AND AN UNFILLED D BLOCK THEN ITS AN EXCEPTION
Which elements are exceptions to the aufbau principle?
Copper, Chromium, and Silver
copper and chromium electron configuration ending
COPPER: 4s ^ 1
3d ^ 10
CHROMIUM: 4s ^ 1
3d ^ 5