electrolysis of aqueous solutions Flashcards
what does aqueous mean
dissolved in water
what do water molecules ionise(split) into
hydrogen ions(H+) and hydroxide ions(OH-)
when is hydrogen produced at the cathode
if the metal is more reactive than hydrogen
why is platinum often used as an electrode
very unreactive
what is the half equation for the cathode
Cu2+ + 2e- – Cu (reduction)
what is the half equation for the anode
4OH- – O2 + 2H2O + 4e- (oxidation)
what happen if the aqueous solution contains halide ions
the halogen will be produced at the anode
what is a halide ion
negatively charged ions that are made up of a halogen atom and an extra electron.
half equations for aqueous sodium chloride
cathode = 2H+ + 2e- – H2
anode = 2Cl- – Cl2 + 2e-