Electrolysis Flashcards
What is electrolysis?
The splitting up of a compound using electricity
What is the half equation for the electrolysis of lead
Pb–>Pb 2+ +2e-
What is the equation for the formation pf bromine
2Br+2e- –> 2Br-
What state mus the compound be in for electrolysis
Liquid (aqueous solution) or molten
What is the cathode
The negative terminal, full of electrons
What is the anode
Positive terminal, lack of electrons
Why are the elements in the compounds attracted to the cathode or anode
Because opposites attract
What is oxidation
The loss of electrons
What is reduction
Gain of electrons
Where does oxidation occur
At the anode
Where does reduction occur
At the cathode
What is an aqueous solution
Something dissolved in water
What happens to water molecules during electrolysis
They also ionise, forming hydrogen ions (+) and hydroxide ions (-)
What is a reversible reaction
A reaction that can happen both ways
What happens at the anode during the electrolysis of NaCl dissolved in water
The chloride ions lose one electron each at the positive anode, pair up and become chloride gas (oxidation). The hydroxide ions get left behind in the solution
What is the half equation for chlorine at the anode
2Cl+ –> Cl(2) + 2e-
What happens to sodium at the cathode
The sodium is more reactive than the hydrogen, meaning that hydrogen gas is released (H2). This means that sodium ions are left behind in the solution
What is the half equation for what happens at the cathode during the electrolysis of NaCl
2H+ + 2e- –> H2
What are the rules of electrolysis for positive ions
If the metal is less reactive then hydrogen, then it forms at the cathode, but if it is more reactive than hydrogen, then hydrogen gas is released at the cathode
What are the rules pf electrolysis for negative ions
If halide (group 7) ions are present, they will be released at the anode. Next, is hydroxide ions,releasing oxygen at the anode. Half equation ( 4OH- –> 2H2O + O2 + 4e-). Any larger ions come next
What is the overall equation for the electrolysis of aluminium oxide
2Al2 O3 (l) –> 4Al (l)+ 3O2 (g)
Why are electrodes made from carbon graphite
Because they are solid, unreactive and good conductors
What is the half equation for the aluminium in aluminium oxide
Al3+ (l) + 3e- –>Al (l) (reduction)
What is the half equation for the oxygen in the aluminium oxide
2O2- (l) –> O2 (g) + 4e- (oxidation)