Electrolysis Flashcards
An electric current is
A flow of electrons or ions
Covalent compounds - conduct electricity?
NO- because the electrons are shared so are fixed in a certain position and are not able to move freely and conduct electricity.
Ionic compounds - conduct electricity?
NOT when solid because the ions aren’t free to move
YES when molten or in solution because the ions can move freely
Electrolysis is
A chemical change caused by passing on electric current through a compound that is either molten or in solution
An Electrolyte is
A substance that undergoes electrolysis. Covalent compounds AREN’T because they don’t contain ions
Anode
Positive electrode
Cathode
Negative electrode
PANC
Positive Anode Negative Cathode
Charges of common positive ions (cations) - 1+
H+ Na+ Ag+ K+ Li+ NH4+
Charges of common positive ions (cations) - 2+
Ba2+ Ca2+ Cu2+ Mg2+ Zn2+ Pb2+ Fe2+
Charges of common positive ions (cations) - 3+
Fe3+
Al3+
Testing for cations (Flame tests)
-Dip a platinum wire in Hydrochloric Acid and then into the solid, then into flame Li+ Red flame Na+ Strong orange flame K+ Lilac flame Ca2+ Brick red flame
Testing for cations (Precipitation reactions)
-Add sodium hydroxide solution to the solution containing:
NH4+, Ammonia = No precipitate is formed but there will be a strong smell and when heated will turn damp litmus blue -ALKALINE
Cu2+, Copper = Blue precipitate (Copper ll hydroxide)
Fe2+, Iron ll = Green precipitate (Iron ll hydroxide)
Fe3+, Iron lll = Orange- brown precipitate (Iron lll hydroxide)
Charges of common negative ions (anions) - 1-
Cl- Br- F- I- HCO3- OH- NO3-
Charges of common negative ions (anions) - 2-
O2-
S2-
SO42-
CO32-
Testing for anions (Chlorine, Bromine + Iodine)
-Add enough dilute nitric acid to make your solution (in water) acidic and then add sliver nitrate solution
Cl- = white precipitate (silver chloride) Br- = pale cream precipitate (silver bromide) I- = yellow precipitate (silver iodide)
Testing for anions (Sulfates)
-Add enough dilute hydrochloric acid to make your solution (in water) acidic and then add barium chloride solution
SO42- = white precipitate (barium sulfate)
Testing for anions (Carbonates)
-Add dilute nitric acid and look for bubbles of gas produced and collect, test for Carbon Dioxide
CO32- = bubbles of CO2
Half equations at cathode
Cu2+(aq) + 2e- –> Cu(s)
Half equations at anode
2I-(aq) –> I2(aq) + 2e-
OILRIG
Oxidisation Is Loss of electrons Reduction Is Gain of electrons
Reducing agent
Substance that reduces something else (gives it electrons)
Oxidising agent
Substance that oxidises something else (takes its electrons)
Redox reaction
Where both oxidisation and reduction occur