Electrolysis Flashcards
What are electrolytes?
The liquid that conducts electricity
What is electrolysis?
Electrolysis is when you pass an electric current through an ionic substance that is molten or in solution and breaking it up forming 2 new substances
Using electricity to break up an ionic compound
Why does the ionic substance have to be molten or in solution in electrolysis?
So they can carry a charge as there are free ions
Will a current flow through an ionic compound that’s solid?
No
If the electrolyte is a non electrolyte will current flow?
No
Is the anode positive or negative electrode?
P A N I C
Anode is positive
Is the cathode the negative or positive electrode?
P A N I C
Cathode is negative
What’s are cations in electrolysis?
Positive ions which are attracted to the cathode which is negative
What are anions in electrolysis?
Anions are negative ions which are attracted to the anode which is positive electrode
Why can’t covalent substance conduct electricity?
Because there are no free ions to carry a charge in covalent substance
What does panic stand for?
Positive Anode Negative Is Cathode
When electrons are taken from the anode (positive) they are given to the?
Cathode (negative)
Electrolysis of lead bromide
Where is lead produced and where is bromine produced?
Lead is produced at the cathode
Bromine is produced at the anode
In the electrolysis of lead bromide what is the electrolyte?
Molten lead bromide
What is the half equation for the cathode in the electrolysis of lead bromide?
Pb 2+ + 2e- ——> Pb
What is the half equation for the anode in the electrolysis of lead bromide?
2Br- ——> Br2 +2e-
If electrolysis happens in aqueous solution what extra ions will there be?
H+ ions and OH- ions
In electrolysis in aqueous solution what is produced at the cathode?
H+ ions and metal ions are present
Hydrogen will be formed if the metal is more reactive but a solid metal layer will be produced if the metal is less reactive than the H+ ions
In electrolysis in aqueous solution what is produced at the anode?
OH- ions and if halide ions are present then they are produced. If no halide ions oxygen is produced
What ions are there in sulphuric acid?
2-
SO Ions
4
\+ And H Ions - And OH Ions
What is produced at the cathode in the electrolysis of sulphuric acid?
H+ ions
Hydrogen is produced
What is the half equation at the cathode for sulfuric acid?
2H+ + 2e- —–>H2
Do hydroxide ions lose electrons more easily or less easily than sulphate ions in the electrolysis of sulfuric acid?
Hydroxide lose electrons more easily than sulphate ions
What is produced at the anode in the electrolysis of sulfuric acid?
Oxygen and water
Oxygen is produced because there are no halide ions
What ions are in sodium chloride?
Na+
Cl-
H+
And OH-
What is produced at the anode and cathode in the electrolysis of sulfuric acid?
anode- oxygen
Cathode -hydrogen
Do hydrogen ions accept electrons more easily or less easily than sodium ions in the electrolysis of sodium chloride?
More easily
Hydrogen more reactive than sodium
What is produced at the cathode in the electrolysis of sodium chloride?
Hydrogen gas is produced
H+ ions
What is the half equation at the cathode in the electrolysis of sodium chloride?
2H+ + 2e- ——> H2
Do chlorine ions lose electrons more easily or less easily than hydroxide ions in the electrolysis of sodium chloride?
More easily
Chlorine in more reactive
What is produced at the anode in the electrolysis of sodium ?
Chlorine gas
Cl-
What is the half equation for the anode in the electrolysis of sodium chloride?
2Cl- ——>Cl2- + 2e-
What ions does copper sulphate contain?
Cu2+ ions
2- So4 Ions
H+ ions
OH- ions
Does hydrogen lose electrons more or less easily than copper in the electrolysis of copper sulfate?
Less easily
Copper loses them more easily
What is produced at the cathode in the electrolysis of copper sulfate?
Pure copper metal
What is the half equation for the cathode in the electrolysis of copper sulfate?
Cu2+ + 2e- —–> Cu
Do hydroxide ions lose electrons more easily or less easily than sulfate ions in the electrolysis of copper sulfate?
More easily
What is produced at the anode in the electrolysis of copper sulfate?
Oxygen and water
OH- ions
What is the half equation for anode in the electrolysis of copper sulfate?
4OH- ——> O2 + 2H2O + 4e-
What is produced at the Anode and cathode in the electrolysis of sodium chloride?
Anode- chlorine
Cathode - hydrogen
What is produced at the anode and cathode in the electrolysis of copper sulfate?
Anode- oxygen
Cathode - copper