electrolysis Flashcards
What is an ion?
An atom that has gained or lost electrons to become stable.
positive = cation
negative = anion
What is electrolysis?
Process where electrical energy decomposes electrolytes
What are the components in electrolysis?
Electrode - rod of metal where current flows
Electrolyte - molten ionic compound
Anode - positive electrode
Anion - negative ion
Cathode - negative electrode
Cation - positive ion
What is PANIC and OILRIG?
Positive is anode, negative is cathode
Oxidation is loss, reduction is gain
Electrolysis in anode?
Oh- ions attracted. If halide ions are present then its discharged at anode, loses electrons & forms a halogen. If no halide ions are present OH- is discharged at anode, loses electrons & forms O2.
Electrolysis in cathode?
H+ ions attracted. Either hydrogen or metal produced. If the metal is above hydrogen in reactivity series, hydrogen will be produced.
What are electrode products?
Anode: brown fumes of bromine gas
Cathode: grey bead of molten lead
What will the products of the electrodes always be?
Anode: non metal
Cathode: metal
REDOX reactions at the electrodes?
Anode: ions are oxidised
Cathode: ions are reduced
What is the method for electrolysis?
- Use measuring cylinder to add 40 ml of copper sulfate into beaker
- Measure & record masses of 2 pieces of copper foil, labelling one the anode, & one the cathode
- Attach cathode to negative terminal of a dc supply, & anode to positive terminal
- Turn on power supply, adjust to achieve constant current & observe what happens at each electrode
- After 10 mins, turn off power &
carefully remove electrodes & allow all liquid to evaporate - do not wipe the electrodes clean - Measure & record mass of electrode
- Repeat experiment again with new electrodes & different currents