Electrode Potentials and Electrochemical Cells Flashcards
Based on electrode potentials, what is the strongest oxidising or weakest reducing agent?
The ion with the most positive value
Based on electrode potentials, what is the weakest oxidising or strongest reducing agent?
The ion with the most negative electrode potential
What are the standard conditions for electrode potentials?
298k
100kPa (only for gas!!!)
1moldm^3
Why is hydrogen fuel not carbon neutral?
Co2 is released as fossil fuel is burned to generate hydrogen
Suggest a possible salt for a salt bridge
Potassium nitrate kNO3 solution unless half cells have either potassium or nitrogen
Or potassium chloride
Which way do electrons flow in an electrochemical cell?
To the reduced ion, away from the oxidised ion
What type of reaction goes on in a cell?
Redox
What electrode should be used for Fe3+?
Platinum bc it’s inert and allows for the flow of electrons
Graphite can be used as an alternative
Why are electrode potentials always written as a reduction reaction?
Because they are being compared to the standard hydrogen electrode
Which half cell will reduce which?
The more positive the electrode will oxidise the more negative electrode
Which half cell will be reduced?
The more positive half cell
How do you work out the electrode potentials of cell?
RHS-LHS
Reduced-oxidised
More positive-more negative
What is the value of the standard hydrogen electrode?
0.00V
EMPIRIO
E Most Positive Is Reduced It Oxidises
What is the purpose of a salt bridge?
To complete the circuit
To allow ions in the ionic substance in the salt bridge to move through the salt brigdhe