Electrochemistry1 Flashcards

1
Q

Oxidation

A

Loss of Electrons

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2
Q

Reduction

A

Gain of Electrons

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3
Q

ELECTRONS MOVE FROM

REACTANT WITH ….. TO REACTANTS WITH ….

A

LESS
ATTRACTION FOR ELECTRONS…
…TO REACTANT WITH MORE
ATTRACTION FOR ELECTRONS

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4
Q

Electronegativity increases

A

upwards and to the right, with N, O, F being the most electronegative atoms in the periodic table

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5
Q

Oxidizing Agent

A

causes oxidation in another species (is reduced)

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6
Q

Reducing Agent

A

causes reduction in another species (is oxidized)

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7
Q

How would you define the O.N.?

A

The O.N. is the charge that the atom would have IF the electrons
were transferred completely to/from bonded atoms

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8
Q

O.N. number of an atom in its elemental form

A

An atom in its elemental form – oxidation number = 0 (e.g. Na or Cl2)

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9
Q

O.N. of a monoatomic ion

A

Monoatomic ion: Oxidation number = ion charge

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10
Q

O.N. of a molecule

A

The sum of oxidation numbers for all atoms in a molecule is equal to the charge on the molecule

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11
Q

O.N. assigned to a group 1 atom

A

Grp1 (+1)

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12
Q

O.N. assigned to a group 2 atom

A

Grp2 (+2

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13
Q

O.N. assigned to a H atom

A

H (+1)

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14
Q

O.N. assigned to a F atom

A

F (-1)

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15
Q

O.N. assigned to an O atom (most cases)

A

O (-2)

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16
Q

O.N. assigned to a group 17 atom

A

Grp17 (-1)

17
Q

What are groups in the periodic table?

A

they are the columns of the periodic table

18
Q

Oxidation

A

O.N. increases (becomes less electronegative)

19
Q

Reduction

A

O.N. decreases (becomes more electronegative)

20
Q

IN A BALANCED REDOX EQUATIONS:

A
# ELECTRONS LOST (OXIDATION)
= # ELECTRONS GAINED (REDUCTION)
21
Q

What is step 1 in balancing Redox Equations?

A
  1. Break “skeleton” equation (no spectator ions) into two half-reactions
22
Q

What is step 2 in balancing Redox Equations?

A
  1. Balance atoms, everything but O&H, then O (add H2O), then H (add H+)
23
Q

What is step 3 in balancing Redox Equations?

A
  1. Balance charge, add electrons (e–) to more positive side
24
Q

What is step 4 in balancing Redox Equations?

A
  1. Scale (multiply) both halves so # electrons are equal, add coefficients
25
Q

What is step 5 in balancing Redox Equations?

A
  1. Add balanced half-reactions together, add spectator ions & states of matter
    (if basic solution, add one OH– to each side for every H+ at this stage)
26
Q

Redox in Organic Chemistry

A

OXIDATION: ADD OXYGEN OR REMOVE HYDROGEN
REDUCTION: REMOVE OXYGEN OR ADD HYDROGEN