Electrochemistry Flashcards

1
Q

Is a device that can generate electrical energy from the chemical reactions occurring in it. Also called galvanic cells or Voltaic cells.

A

electrochemical cell

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2
Q

It is defined as a chemical reaction involving the transfer of electrons between two electrodes in an electrochemical cell

A

electrochemical process

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3
Q

Late 18th century, he discovered the bimetallic driving force

A

Luigi Galvani

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4
Q

In 1800, he invented first electrical cell, or battery: a series of metal disks of two kinds, separated by cardboard disks soaked with acid or salt solutions.

A

Alessandro Volta

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5
Q

Early 19th century- He engineered into the useful protection of metallic structures.

A

Sir Humphry Davy

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6
Q

It is the tendency for an electrode to lose or gain electrons when dipped in the solution of its ions.

A

electrode potential

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7
Q

A device used in an electrochemical cell for connecting its oxidation and reduction half cells wherein an inert electrolyte is used

A

salt bridge

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8
Q

It is a medium that provides the ion transport mechanism between the cathode and anode of a cell.

A

electrolyte

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9
Q

Type of electrochemical cell which involve different types of metals/ nonmetal composition coming into contact, leading to electron transfer between them.

A

dissimilar electrode cell

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10
Q

Type of electrochemical cell with two identical electrodes, each in contact with a solution of different composition

A

salt concentration cell

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11
Q

Type of electrochemical cell when two identical electrodes are immersed in same electrolyte, but the electrodes are immersed into solution of two different temperatures.

A

differential temperature cell

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12
Q

A list that describes the arrangement of elements in the order of their increasing electrode potential values.

A

electrochemical series

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13
Q

An orderly arrangement of the standard potentials for all metals

A

electromotive force series/ galvanic series

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14
Q

It is use in the standard hydrogen electrode since it is relatively inert, has catalytic qualities, surface can be platinized, and improve reaction kinetics.

A

platinum

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15
Q

Pure mercury is placed at the bottom of the tube, which is covered with a paste of mercury-mercurous chloride. Pure mercury covers a platinum wire sealed through the bottom of a glass tube.

A

calomel reference electrode

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16
Q

It is composed of a silver wire, sometimes coated with a layer of solid silver chloride

A

silver-silver chloride reference electrode

17
Q

It consists of a metallic copper immersed in saturated copper sulfate. It is use where the electrode must be resistant to shock.

A

saturated copper-copper sulfate reference electrode

18
Q

Relate the current of an electrochemical reaction to the number of moles of the element being reacted and the number of moles of electrons involved.

A

Faraday’s law of electrolysis

19
Q

If Sc/Sa is > 1

A

amplifying factor

20
Q

If Sc/Sa is < 1

A

stifling factor

21
Q

____ occurs when the electrolyte resistance is so high that the resultant current is not sufficient to polarize anodes or cathodes

A

resistance control

22
Q

The _____ can be calculated from the corrosion potential and the thermodynamic potential

A

corrosion current

23
Q

If the metal is polarized slightly beyond the open-circuit potential of the anode, the corrosion rate remains ____.

A

zero