Corrosion of non-metals Flashcards
Occur when polymers are exposed to heat above a specified temperature limit
Chain Scission from Heat
In the presence of oxygen, UV radiation can cause a breakdown of the polymer chains
Breakdown of Chains from UV Radiation
Absorption of water at elevated temperatures causes _____ of certain groups in a polymer chain
Hydrolysis
Are substances composed of macromolecules, very large molecules with molecular weights ranging from a
few thousand to as high as millions of
grams/mole.
polymers
Is the penetration of the plastic by a corrodent, which causes softening, swelling, and ultimate failure.
Solvation
Is caused by photons or light-breaking chemical bonds.
Photochemical degradation
The breakup of molecules into smaller pieces by photons
photodissociation
Is a molecular migration through micro voids either in the polymer or between polymer molecules.
Permeation
Driving force of diffusion
Partial pressure of gases
Concentration gradient of liquids
Is a function of the affinity of the permeant for the polymer.
Solubility
Polymers have the potential to soak up varied amounts of corrodents, especially organic liquids.
Absorption
Is a material that is neither metallic nor organic. It may be crystalline, glassy or both crystalline and glassy.
ceramic
____ in a ceramic takes place as a result of chemical dissolution.
Uniform corrosion
The corrosion process of a solid material by a liquid can involve the formation of an interface or reaction product between the solid and the solvent.
Indirect Dissolution
The solid material dissolves directly into the liquid through dissociation or reaction with the solvent.
Direct Dissolution
Is typically manufactured to harness the optimal properties of two or more materials, aiming to enhance overall performance or capture specific attributes of each component.
composite / Fiber-Reinforced Polymer (FRP)
A composite that exhibits good heat resistance up to around 500°C but experience significant strength reduction at higher temperatures due to increased oxidation rates.
Boron fibers
Composite that is highly stable in oxidizing atmospheres up to 1090°C, while boron nitride is stable only up to 850°C.
Boron carbide