electrochemistry Flashcards
Oxidation Number or State
The apparent charge on an atom of an element in a molecule or in an ion is called
oxidation state or oxidation number of that atom.
Example:
In
+1 _1
H Cl
, oxidation state of hydrogen is +1 and that of Chlorine is -1.
Electronegativity and oxidation number:
In any substance, the more electronegative atom has the negative oxidation number
while less electronegative element is given the positive oxidation number.
Conduction is of two types.
(i) Electrolytic conduction
(ii) Electronic or metallic conduction
Electrolytic Conduction:
The conduction in which current is carried by positively and negatively charged ions is solution or in fused state is called electrolytic conduction.
Electronic Conduction or Metallic Conduction:
The conduction of electricity due to free movement of electrons in the metallic lattice is called electronic conduction or metallic conduction.
Ionization:
The process of splitting of ionic compounds into charged particles when fused or dissolved in water is called ionization.
Electrolysis:
The process in which non – spontaneous reaction takes place at the expense of electricity is called electrolysis.
Electrochemical Cells:
A cell or a system which consists of electrodes dipped into an electrolyte in which a redox chemical reaction uses or generates electric current is called electrochemical cell.
Types of Electrochemical Cells:
There are two types of electrochemical cells.
1.Electrolytic cell
2.Voltaic or galvanic cell