Electrochemical and Electrolytic Cells Flashcards

1
Q

What is the purpose of the electrolyte?

A

Allows for only movement of ions between electrodes. Maintain charge neutrality.

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2
Q

What is a Fuel Cell

A

A fuel cell is a type of galvanic cell which converts chemical energy to electrical energy using a continuous supply of reactants.

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3
Q

What is a Direct Reaction

A

Chemical energy being converted to Heat Energy

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4
Q

What is an Indirect reaction

A

Chemical energy being converted to electrical energy

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5
Q

What if there is a SMALL difference in electric potential within a Galvanic Cell

A

Other reactions may occur. e.g. ‘whiff of chlorine’

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6
Q

Why do Fuel Cells use POROUS electrodes

A

Porous electrodes allow for gas to access electrolyte and it has a large SURFACE AREA

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7
Q

What are advantages of Fuel Cells

A

High Energy Conversion efficiency
Low running costs
Low chemical pollution

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8
Q

What are disadvantages of Fuel Cells

A

Initial cost is expensive
Continuous supply of fuel
H2 gas is difficult to store

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9
Q

List KEY differences between Galvanic and Fuel Cells

A

Galvanic - carbon electrodes, separate vessel, requires continuous supply

Fuel cell - porous electrodes, same vessel, contains products and reactants

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10
Q

Why is a fuel cell considered renewable

A

H2 that is produced do not require large land to produce. No release of CO2

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11
Q

What are the 2 types of Electrohemical Cells

A

Primary and Secondary

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12
Q

Outline the difference between Primary and Secondary Cells

A

Primary: Non-rechargable, uses porous separators
Secondary: Rechargable, no need for separator as reaction is non-spotaneous

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13
Q

What are the conditions for a secondary cell to be rechargeable

A

Products of discharge reaction must stay at electrodes

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14
Q

Outline the 2 reactions in a secondary cell

A

Discharge - chemical –> electrical

Recharge - electrical –> chemical

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15
Q

What affects Battery life of secondary cells

A

High temp –> decreases battery life
Low temp –> decreases ROR –> decrease energy
Corrosion
Products do NOT stay at electrodes

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16
Q

What is electrolysis

A

Electrical –> chemical

17
Q

DIfference between Electrolysis and Galvanic

A

Ele - Produces Chem energy, Anode is +ve, no separator

Galvanic - Produces Elec energy, Anode is -ve, separator

18
Q

What is Faraday’s 1st and 2nd Law

A

1st - mass of metal is DIRECTLY proportional to charge applied

2nd - Amount deposited is reciprocal of the charge of ion

19
Q

What is the purpose of electrodes

A
  • Site of Reduction and Oxidation
  • Complete the circuit
  • Conduct electricity
20
Q

Why is using an abrasive such as steel wool a disadvantage to clean an object

A

This is because it may remove unintended metal such as silver from a coin

21
Q

Why is there a diaphram/separator used

A

Prevents products coming in contact with each other violently

22
Q

Identify 2 features of the electrodes of a fuel cell

A

Porous electrodes = allow for gas to access electrodes

Conductive material