Elastomers Flashcards

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1
Q

What are the two types of elastomers?

A
  • Polyether
  • Addition silicones
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2
Q

What is meant by elastic behaviour for impression materials?

A
  • When removing IM from contact with tooth after it has set
  • IM has to stretch and flares out at sides to overcome bulbous aspect of tooth
  • Ideally it recovers to original dimension, replicating shape of tooth
  • Assumes perfectly elastic
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3
Q

How are elastomers formed?

A
  • Formed by polymerisation with cross-linking of polymer chains
  • Polymerisation may produce by-products like water or hydrogen which affect dimensional stability and cast compatibility
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4
Q

What does the cross-linking generate?

A
  • Elastic properties
  • Causes fluid to solid transition
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5
Q

What 3 mechanical properties of elastomers affect the accuracy by which the surface features are recorded?

A
  • Surface details (reproduction)
  • Flow/viscosity
  • Contact angle/ wettability
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6
Q

What 3 mechanical properties affect accuracy of the dimensions and shape of final impression?

A
  • Elastic recovery %
  • Stiffness (flexibility)
  • Tear strength
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7
Q

What is Shore A hardness?

A
  • Specific hardness test for IM
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8
Q

What is the shark fin test?

A
  • Relates to ability of IM to deal with undercuts
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9
Q

What other mechanical properties are important for Elastomers?

A
  • Shore A hardness
  • Shark fin test (flow under P)
  • Setting shrinkage
  • Dimensional stability
  • Thermal expansion coefficient
  • Biocompatibility
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10
Q

What is VIRTUAL?

A
  • An addition polyvinylsiloxane
  • Made by IVPCLAR-VIVADENT
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11
Q

What are the important properties of VIRTUAL?

A
  • Has good hydrophillic properties during impression taking ( good for fine detail of oral hard and soft tissues)
  • Good compatibility with moist dentin and gingival tissue
  • Exhibit very low contact angles with excellent wettability
  • Excellent moisture displacement
  • Colour contrast gives margins that are easy to read
  • Precise impressions
  • High tear strength
  • Hardness adjusted to clinical needs
  • Good elastic recovery
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12
Q

What is Viscosity?

A
  • Measure of materials ability to flow
  • Determines a materials potential for making close contact with hard/soft tissue surface so how well it records fine detail
  • Range can be low, medium or high
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13
Q

What does the contact angle indicate?

A
  • How readily ‘wet’ the tooth surface is and how closely the IM envelops the tooth surface
  • Low contact angle means large % of its vol make contact with target surface = no space between globules of IM = ideal
  • Large contact angle = spaces between globules of IM = some surface not replicated
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14
Q

What are hydrophilic silicones?

A
  • Non ionic surfactant
  • Incorporated into addition silicones as they have difficulty making good contact with moist tooth surface
  • They wet tooth surface
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15
Q

What is the ISO 4823?

A
  • International standard measure for surface reproduction of IM
  • Measures how accurately surface is represented
  • Test involves placing IM along surface which has grooves of 20, 50 and 75um
  • Uniform pressure applied across width of IM
  • An IM that record the 20um grooves gives most accurate surface detail
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16
Q

Are Impression material truly elastic?

A
  • No they are all Visco-elastic to some extent
  • When load applied IM will gradually reach strain required
  • When load released strain gradually drops
  • Does not return to original dimension and experiences permanent deformation (aka permanent strain)
17
Q

What is definition of Viscoelastic behaviour?

A
  • Occurs when, after being stretched or compressed, a material fails to return to its original dimensions/shape and there is permanent deformation
18
Q

How is viscoelastic behaviour influenced by tray removal method?

A
  • If load time is less and impression tray removed with sharp pull then less overall permanent strain (lower deformation)
19
Q

When does the IM elasticity begin to develop?

A
  • IM ability to flow diminishes
  • Only when setting reaction progressed to certain extent does materials elasticity begin to develop fully
  • Even when IM firm to touch it is still developing elasticity
  • Wait a few mins before removing it
20
Q

What is the shark fin test?

A
  • Used to record an undercut
  • Undercut can only be recorded when IM reaches the narrow zone (between the gingivae and tooth surface)
  • IM inserted into cylindrical chamber that has slot of specified depth and forced down (pressure applied)
21
Q

What does large fin length and short fin length mean on shark fin test?

A
  • Large fin length means high flow and will flow readily into sulcus and undercuts
  • Short fin length has low flow
22
Q

What is the tear strength?

A
  • Stress material will withstand before fracturing
23
Q

What is rigidity?

A
  • stress/strain ratio
  • Stress needed to cause material to change shape
24
Q

What is an example of Polyether elastomer?

A
  • Impregum Penta soft (medium)
25
Q

What are some examples of addition silicone elastomer?

A

Aquasil Ultra (monophase)
VIRTUAL (monophase)
Flexitime (monophase)

26
Q

How to use the best decision-making approach when choosing IM?

A
  1. Know KEY material properties
    - be prepared for new terminology, & sales pitch.
  2. Review product specification data
    – cf best rival products?
  3. Know typical values expected for specific properties
  4. Identify properties NOT mentioned
  5. REJECT claims NOT supported with scientific/clinical data
27
Q

What are the key properties summary?

A

Viscosity - Flow across surface - Low

Contact angle (wettability) - Engagement with tooth surface/surface quality - Low (high)

Viscoelasticity - Deformation on removal - Low

Stiffness - Ease of removal from undercut - Low

Thermal expansion - contraction - mouth room temp - Low

Polymerisation shrinkage - Contraction during setting - Low

Tear resistance - ability to withstand large stresses during removal - High but not too high