EL.8 Flashcards

Group 1 and group 2 chemistry

1
Q

Elements of which groups belong in the s block?

A

Group 1 and 2.

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2
Q

How does reactivity change as you go down group 1 and 2?

A

Elements become more reactive, the most reactive metals are found at the bottom of each group

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3
Q

What trend does the elements in group 1 and 2 show in terms of becoming ions?

A

As you go down the groups, elements lose electrons easier and form cations more readily in ionic compounds. These elements are said to become more metallic as you go down the groups.

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4
Q

How does reactivity change as you move across the periodic table from the left to the right in terms of from group 1 to group 2?

A

They become less reactive. Group 1 metals are more reactive than group 2 metals in the same period. These elements are said to become less metallic as you move across the periods.

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5
Q

What are some descriptions for the physical properties of the s block metals?

A

They tend to be soft , weak metals with low melting points.

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6
Q

What reactions of s block metal make them not so useful in daily life?

A

They are too reactive with oxygen and water to become oxides and hydroxides.

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7
Q

How are group 1 and 2 metals normally found?

A

In compounds with other elements, they are never naturally found in their elemental form.

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8
Q

In group 1 and 2, elements show similarities in their reactions with elements in their group, and differences are also observed in groups as trends. What features about elements in the same group can be used to explain the similarities, and what can explain the differences?

A

Similarities of elements in the same group happen because of their similar arrangement of electrons in their atoms. The differences, on the other hand, happen because the size of atom increases down the group.

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9
Q

What does ionization mean?

A

The process of removing or adding an electron to an atom so it becomes an ion.

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10
Q

What is the energy required to remove one electron from an atom known as?

A

First ionization enthalpy

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11
Q

What is the general equation for the first ionization process?

A

X(g) → X+(g) + e-

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12
Q

What are some conditions to be included when stating the first ionization enthalpy of an element?

A

It is the amount of energy required to remove one electron from one mole of atoms of that element in its gaseous form.

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13
Q

Which electron would be removed in first ionization?

A

The most loosely held electron, this will be one of the outer shell electrons.

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14
Q

Elements from which group have the highest first ionization enthalpies?

A

Group 0, noble gases, they are extremely stable and very difficult to ionize.

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15
Q

Elements from which group have the lowest first ionization enthalpies?

A

Group 1, with only one outer shell electron, they are very reactive and very easy to ionize.

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16
Q

What is the general trend in first ionization enthalpy across a period and what is the reason for this trend?

A

As you go across a period, it becomes more difficult to remove an electron, the ionization enthalpy show a general increase. This is because as electrons are being added to the outer shell, protons are being added to the nucleus too. And as the nuclear charge becomes more positive, electrons in the outer shell are held more tightly, making them more difficult to remove going across a period.

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17
Q

Although the general trend in ionization enthalpy across a period is an increase, there are some variations. What are reasons that may result in these variations?

A
  • New electrons being added to p sub shells.

- Extra repulsion from paired electron sub shell making one easier to remove.

18
Q

What is the general trend in first ionization enthalpy going down a group and what is the reason for this trend?

A

As you go down a group, it becomes easier to remove an electron, the ionization enthalpy show a decrease. This is because the attraction between the nucleus and the outer shell electrons decrease.

19
Q

What is the general equation for the second ionization process?

A

X+(g) → X2+(g) + e-

20
Q

What are successive ionization enthalpies a measure of?

A

Energy required to remove a electron from a cation (the charge of the cation dependence on which ionization enthalpy it is), not the energy require to remove a certain number of electrons at once from an atom.

21
Q

What is the general equation for group 2 metals reacting with oxygen to produce metal oxide?

A

2M(s) + O2(g) → 2MO(s)

22
Q

Which of the group 2 metals can react with oxygen to form metal oxide?

A

All of them.

23
Q

What is the general equation for group 2 metals reacting with water to produce metal hydroxide and hydrogen?

A

M(s) + 2H2O(l) → M(OH)2(aq) + H2(g)

24
Q

Which of the group 2 metals can react with water to form metal hydroxide and hydrogen?

A

All of them.

25
Q

What is the trend in reactivity of group 2 metals with water?

A

Increase in reactivity as you go down the group.

26
Q

How does group 2 metals’ reactivity with water to that of group 1 metals’?

A

They are less reactive with water compare to group 1 metals.

27
Q

What is the formula of a carbonate ion?

A

CO3 2-

28
Q

What is the general formula of group 2 carbonates?

A

MCO3

29
Q

What is the general equation of the decomposition of group 2 carbonates on heating?

A

MCO3(s) → MO(s) + CO2(g)

30
Q

What is the trend in the difficulty of the decomposition of group 2 carbonates?

A

The carbonates become more difficult to decompose as you go down the group.

31
Q

What does thermal stability mean?

A

How much heat the compound can withstand before it eventually decomposes.

32
Q

What is charge density?

A

It is the measure of the concentration of charge on an ion.

33
Q

How does the charge density of the group 2 cation change down the group?

A

Smaller ions have higher charge densities, therefore as you go down group 2 ions, their charge densities decrease.

34
Q

How can the increase in thermal stability of group 2 carbonate be explain by the decrease in charge density of the metal cations?

A

Cations with higher charge density (towards the top of the group), can distort or polarize the negative charge cloud around the carbonate ion, making the ionic bond less stable and easier to break/decompose on heating.

35
Q

What is the general formula of group 2 oxides?

A

MO

36
Q

What is the general formula of group 2 hydroxides?

A

M(OH)2

37
Q

What does oxides and hydroxides do to the pH of the water when dissolved in water?

A

Increase pH, making an alkaline solution. Although they tend to be not very soluble.

38
Q

Metal hydroxides and oxides typically form alkaline solutions, how about oxides of non metals?

A

They are usually acidic.

39
Q

What is the trend in pH of group 2 oxides and hydroxides?

A

Increasing pH as you go down the group, they get more alkaline.

40
Q

What is the trend in solubility of group 2 hydroxides?

A

They get more soluble as you go down the group.